Wetting hysteresis and droplet roll off behavior on superhydrophobic surfaces by Katherine Marie Smyth.

Abstract

Various states of hydrophobic wetting and hysteresis are observed when water droplets are deposited on micro-post surfaces of different post densities. Hysteresis is commonly defined as the difference between the advancing and receding contact angle and after many decades of research, the mechanisms governing hysteresis are still not fully understood. Particularly, stick-slip behavior of the three-phase contact line has been observed and qualitatively attributed to surface or chemical heterogeneities, but the behavior has yet to be quantified. In this thesis, contact line motion particularly focused on stick-slip behavior and its influence on drop width and contact angle was examined as a new approach to understanding hysteresis as pertaining to micro-textured surfaces. This work focuses on developing a fundamental understanding and physical model of the stick-slip behavior of the contact line and preliminarily explores the influence of contact line velocity on this stick-slip behavior and contact angle. By characterizing stick-slip behavior and hysteresis on micro-post surfaces, models can be developed that in the future can aid in surface design for optimal wetting behavior in industrial and power plant applications. Additionally, the pinning parameter has been used to predict roll off angle on micro-post surfaces for a variety of post densities and these predictions have been experimentally verified. With further definition of the pinning parameter to include surface roughness and impact phenomena, the pinning parameter can be used in surface design for droplet shedding in industrial applications.