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dc.contributor.authorMatsubara, Ryosuke
dc.contributor.authorJamison, Timothy F.
dc.date.accessioned2012-08-14T16:18:36Z
dc.date.available2012-08-14T16:18:36Z
dc.date.issued2011-03
dc.identifier.issn1861-4728
dc.identifier.issn1861-471X
dc.identifier.urihttp://hdl.handle.net/1721.1/72119
dc.description.abstractThis report describes a nickel-catalyzed allylic substitution process of simple alkenes whereby an important structural motif, a 1,4-diene, was prepared. The key to success is the use of an appropriate nickel–phosphine complex and a stoichiometric amount of silyl triflate. Reactions of 1-alkyl-substituted alkenes consistently provided 1,1-disubstituted alkenes with high selectivity. Insight into the reaction mechanism as well as miscellaneous application of the developed catalytic process is also documented.en_US
dc.description.sponsorshipNational Institute of General Medical Sciences (U.S.) (GM-63755)en_US
dc.description.sponsorshipJapan Society for the Promotion of Science. Postdoctoral Fellowship for Research Abroaden_US
dc.language.isoen_US
dc.publisherWiley Blackwell (John Wiley & Sons)en_US
dc.relation.isversionofhttp://dx.doi.org/10.1002/asia.201000875en_US
dc.rightsCreative Commons Attribution-Noncommercial-Share Alike 3.0en_US
dc.rights.urihttp://creativecommons.org/licenses/by-nc-sa/3.0/en_US
dc.sourcePMCen_US
dc.titleNickel-Catalyzed Allylic Substitution of Simple Alkenesen_US
dc.typeArticleen_US
dc.identifier.citationMatsubara, Ryosuke, and Timothy F. Jamison. “Nickel-Catalyzed Allylic Substitution of Simple Alkenes.” Chemistry - An Asian Journal 6.7 (2011): 1860–1875.en_US
dc.contributor.departmentMassachusetts Institute of Technology. Department of Chemistryen_US
dc.contributor.approverJamison, Timothy F.
dc.contributor.mitauthorMatsubara, Ryosuke
dc.contributor.mitauthorJamison, Timothy F.
dc.relation.journalChemistry - An Asian Journalen_US
dc.eprint.versionAuthor's final manuscripten_US
dc.type.urihttp://purl.org/eprint/type/JournalArticleen_US
eprint.statushttp://purl.org/eprint/status/PeerRevieweden_US
dspace.orderedauthorsMatsubara, Ryosuke; Jamison, Timothy F.en
dc.identifier.orcidhttps://orcid.org/0000-0002-8601-7799
mit.licenseOPEN_ACCESS_POLICYen_US
mit.metadata.statusComplete


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