dc.contributor.author | Matsubara, Ryosuke | |
dc.contributor.author | Jamison, Timothy F. | |
dc.date.accessioned | 2012-08-14T16:18:36Z | |
dc.date.available | 2012-08-14T16:18:36Z | |
dc.date.issued | 2011-03 | |
dc.identifier.issn | 1861-4728 | |
dc.identifier.issn | 1861-471X | |
dc.identifier.uri | http://hdl.handle.net/1721.1/72119 | |
dc.description.abstract | This report describes a nickel-catalyzed allylic substitution process of simple alkenes whereby an important structural motif, a 1,4-diene, was prepared. The key to success is the use of an appropriate nickel–phosphine complex and a stoichiometric amount of silyl triflate. Reactions of 1-alkyl-substituted alkenes consistently provided 1,1-disubstituted alkenes with high selectivity. Insight into the reaction mechanism as well as miscellaneous application of the developed catalytic process is also documented. | en_US |
dc.description.sponsorship | National Institute of General Medical Sciences (U.S.) (GM-63755) | en_US |
dc.description.sponsorship | Japan Society for the Promotion of Science. Postdoctoral Fellowship for Research Abroad | en_US |
dc.language.iso | en_US | |
dc.publisher | Wiley Blackwell (John Wiley & Sons) | en_US |
dc.relation.isversionof | http://dx.doi.org/10.1002/asia.201000875 | en_US |
dc.rights | Creative Commons Attribution-Noncommercial-Share Alike 3.0 | en_US |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-sa/3.0/ | en_US |
dc.source | PMC | en_US |
dc.title | Nickel-Catalyzed Allylic Substitution of Simple Alkenes | en_US |
dc.type | Article | en_US |
dc.identifier.citation | Matsubara, Ryosuke, and Timothy F. Jamison. “Nickel-Catalyzed Allylic Substitution of Simple Alkenes.” Chemistry - An Asian Journal 6.7 (2011): 1860–1875. | en_US |
dc.contributor.department | Massachusetts Institute of Technology. Department of Chemistry | en_US |
dc.contributor.approver | Jamison, Timothy F. | |
dc.contributor.mitauthor | Matsubara, Ryosuke | |
dc.contributor.mitauthor | Jamison, Timothy F. | |
dc.relation.journal | Chemistry - An Asian Journal | en_US |
dc.eprint.version | Author's final manuscript | en_US |
dc.type.uri | http://purl.org/eprint/type/JournalArticle | en_US |
eprint.status | http://purl.org/eprint/status/PeerReviewed | en_US |
dspace.orderedauthors | Matsubara, Ryosuke; Jamison, Timothy F. | en |
dc.identifier.orcid | https://orcid.org/0000-0002-8601-7799 | |
mit.license | OPEN_ACCESS_POLICY | en_US |
mit.metadata.status | Complete | |