| dc.contributor.author | Marinescu, Smaranda C. | |
| dc.contributor.author | Schrock, Richard Royce | |
| dc.contributor.author | Muller, Peter | |
| dc.contributor.author | Takase, Michael K. | |
| dc.contributor.author | Hoveyda, Amir H. | |
| dc.date.accessioned | 2012-08-28T16:05:08Z | |
| dc.date.available | 2012-08-28T16:05:08Z | |
| dc.date.issued | 2011-03 | |
| dc.date.submitted | 2011-02 | |
| dc.identifier.issn | 0276-7333 | |
| dc.identifier.issn | 1520-6041 | |
| dc.identifier.uri | http://hdl.handle.net/1721.1/72371 | |
| dc.description.abstract | 3,5-Dimethylphenylimido complexes of tungsten can be prepared using procedures analogous to those employed for other tungsten catalysts, as can bispyrrolide species and MonoAryloxide-Pyrrolide (MAP) species. Homocouplings of 1-hexene, 1-octene, and methyl 10-undecenoate are achieved in 45−89% yield and a Z selectivity of >99% with W(NAr′′)(C[subscript 3]H[subscript 6])(pyr)(OHIPT) as a catalyst. Homocoupling of terminal olefins in the presence of (E)-olefins elsewhere in the molecule also was achieved with excellent selectivity. | en_US |
| dc.description.sponsorship | National Science Foundation (U.S.). (Grant number CHE-0841187) | en_US |
| dc.description.sponsorship | National Institutes of Health (U.S.) (Grant number GM-59426) | en_US |
| dc.language.iso | en_US | |
| dc.publisher | American Chemical Society (ACS) | en_US |
| dc.relation.isversionof | http://dx.doi.org/10.1021/om200150c | en_US |
| dc.rights | Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use. | en_US |
| dc.source | PMC | en_US |
| dc.title | Room-Temperature Z-Selective Homocoupling of alpha-Olefins by Tungsten Catalysts | en_US |
| dc.type | Article | en_US |
| dc.identifier.citation | Marinescu, Smaranda C. et al. “Room-Temperature Z-Selective Homocoupling of α-Olefins by Tungsten Catalysts.” Organometallics 30.7 (2011): 1780–1782. | en_US |
| dc.contributor.department | Massachusetts Institute of Technology. Department of Chemistry | en_US |
| dc.contributor.approver | Schrock, Richard Royce | |
| dc.contributor.mitauthor | Marinescu, Smaranda C. | |
| dc.contributor.mitauthor | Schrock, Richard Royce | |
| dc.contributor.mitauthor | Muller, Peter | |
| dc.contributor.mitauthor | Takase, Michael K. | |
| dc.relation.journal | Organometallics | en_US |
| dc.eprint.version | Author's final manuscript | en_US |
| dc.type.uri | http://purl.org/eprint/type/JournalArticle | en_US |
| eprint.status | http://purl.org/eprint/status/PeerReviewed | en_US |
| dspace.orderedauthors | Marinescu, Smaranda C.; Schrock, Richard R.; Müller, Peter; Takase, Michael K.; Hoveyda, Amir H. | en |
| dc.identifier.orcid | https://orcid.org/0000-0001-5827-3552 | |
| mit.license | PUBLISHER_POLICY | en_US |
| mit.metadata.status | Complete | |
