General Approach to Epipolythiodiketopiperazine Alkaloids: Total Synthesis of (+)-Chaetocins A, C and (+)-12,12'- Dideoxychetracin A

Author(s)
Kim, Justin; Movassaghi, Mohammad
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Abstract
A highly stereoselective and systematic strategy for the introduction of polysulfides in the synthesis of epipolythiodiketopiperazines is described. We report the first total synthesis of dimeric epitri- and epitetrathiodiketopiperazines.
Date issued
2010-09
URI
http://hdl.handle.net/1721.1/73134
Department
Massachusetts Institute of Technology. Department of Chemistry
Journal
Journal of the American Chemical Society
Publisher
American Chemical Society
Citation
Kim, Justin, and Mohammad Movassaghi. “General Approach to Epipolythiodiketopiperazine Alkaloids: Total Synthesis of (+)-Chaetocins A and C and (+)-12,12'-Dideoxychetracin A.” Journal of the American Chemical Society 132.41 (2010): 14376–14378.
Version: Author's final manuscript
ISSN
0002-7863
1520-5126
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