An Air-Stable Low-Bandgap n-Type Organic Polymer Semiconductor Exhibiting Selective Solubility in Perfluorinated Solvents
Author(s)Takeda, Youhei; Andrew, Trisha Lionel; Lobez, Jose M.; Mork, Anna Jolene; Swager, Timothy Manning
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Thumbnail image of graphical abstract A thin-film transistor: An n-type polymer semiconductor, poly(2,3-bis(perfluorohexyl)thieno[3,4-b]pyrazine), was synthesized through a Pd-catalyzed polycondensation employing a perfluorinated multiphase solvent system. This is the first example of an n-type polymer semiconductor with exclusive solubility in fluorinated solvents. The fabrication of organic field effect transistors containing this new n-type polymer semiconductor is shown (see picture).
DepartmentMassachusetts Institute of Technology. Department of Chemistry; Massachusetts Institute of Technology. Department of Electrical Engineering and Computer Science
Angewandte Chemie International Edition
John Wiley & Sons, Inc.
Takeda, Youhei et al. “An Air-Stable Low-Bandgap n-Type Organic Polymer Semiconductor Exhibiting Selective Solubility in Perfluorinated Solvents.” Angewandte Chemie International Edition 51.36 (2012): 9042–9046. Web.
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