Browsing Chemistry - Ph.D. / Sc.D. by Title
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Z-selective olefin metathesis processes and Cis/syndioselective ROMP with high oxidation state molybdenum alkylidenes (Massachusetts Institute of Technology, 2012)Chapter 1: Reaction of W(CCMe3)Cl 3(dme) with one equivalent of (3,5-Me 2C6H3NCH2CH 2)3N)Li3 affords yellow, crystalline W(CCMe3)(N3N) in good yield. The reactivity of this new alkylidyne complex towards terminal alkynes ...