Browsing Chemistry - Ph.D. / Sc.D. by Title
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Browsing Chemistry - Ph.D. / Sc.D. by Title
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(Massachusetts Institute of Technology, 2010)In this thesis, dynamics experiments are developed that can be used to study protein conformational changes such as folding and binding. Every functional motion of a protein is inextricably linked to conformational dynamics. ...
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(Massachusetts Institute of Technology, 2005)(Trialkylsilyl)vinylketenes ("(TAS)vinylketenes") and (trialkylsilyl)arylketenes ("(TAS)- arylketenes") function as versatile four-carbon building blocks for the synthesis of carbocyclic and heterocyclic compounds. A new ...
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(Massachusetts Institute of Technology, 2007)Iminoacetonitriles participate as reactive dienophiles in intermolecular and intramolecular Diels-Alder cycloadditions leading to quinolizidines, indolizidines, and piperidines. The resultant a-amino nitrile cycloadducts ...
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(Massachusetts Institute of Technology, 2013)Iminoacetonitriles participate as activated imino dienophiles in intermolecular and intramolecular aza Diels-Alder reactions affording tetrahydropyridines and indolizidines. The [alpha]-amino nitrile cycloadducts are ...
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(Massachusetts Institute of Technology, 1992)
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(Massachusetts Institute of Technology, 1997)
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(Massachusetts Institute of Technology, 1922)
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(Massachusetts Institute of Technology, 1934)
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(Massachusetts Institute of Technology, 1999)
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(Massachusetts Institute of Technology, 2004)Molybdaziridine-hydride Mo(H)([eta]²-Me₂C=NAr)(N[i-Pr]Ar)₂ (1, Ar = 3,5-C₆H₃Me₂) acts as a source of its three-coordinate isomer Mo(N[i-Pr]Ar)₃ (2). This relationship has been probed via an investigation of the coordination ...
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(Massachusetts Institute of Technology, 1920)
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(Massachusetts Institute of Technology, 1996)
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(Massachusetts Institute of Technology, 2008)This thesis describes the construction of a novel, low-noise laser kinetics spectrometer. A quasi-CW (picosecond pulse), tunable Ti:Sapphire laser is used to detect various transient species in laser flash photolysis ...
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(Massachusetts Institute of Technology, 2010)Molecular oxygen is observed to adsorb on 0.2 - 0.6 ML Au/Ni(111) surface alloys. Molecular oxygen adsorbates are characterized by their 0-0 stretching frequencies of 740 cm', 851 cm' and 962 cm', as measured by high ...
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(Massachusetts Institute of Technology, 1978)
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(Massachusetts Institute of Technology, 1998)
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(Massachusetts Institute of Technology, 2011)Chapter 1 A comprehensive review of diiron modeling in the Lippard group over the past thirty years is presented. This account describes the different strategies employed to prepare biomimetic complexes of non-heme diiron ...
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(Massachusetts Institute of Technology, 2017)The determination of the structures of biological systems, such as, fibril-forming peptides and proteins, membrane proteins, and viruses, by solid-state nuclear magnetic resonance (NMR) spectroscopy has materialized as an ...
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(Massachusetts Institute of Technology, 2010)Chapter 1: A highly active catalyst system based upon a biaryl monophosphine ligand, XPhos, for the palladium-catalyzed Stille reaction has been developed. This method allows for the coupling of aryl chlorides with a range ...
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(Massachusetts Institute of Technology, 1995)
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