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Catalytic C-N and C-F bond formation by organometallic group 11 complexes
(Massachusetts Institute of Technology, 2007)
This thesis presents a study of the reaction between an (NHC)gold(I) fluoride complex (NHC = N-heterocyclic carbene) and alkynes (Chapter 1). Gold(I) and fluoride add trans across the triple bond of 3-hexyne and ...