Progress towards the synthesis of tetracyclic heteroaromatic compounds via tandem benzannulation-cyclization strategies
Author(s)
Mamaliga, Galina
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Massachusetts Institute of Technology. Department of Chemistry.
Advisor
Rick L. Danheiser.
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A tandem benzannulation-cyclization strategy was successfully applied to the synthesis of a tetracyclic heteroaromatic compound expected to have interesting electronic properties. Benzannulation of a diazo ketone and a ynamide yielded a highly substituted aniline that was cyclized to indole according to protocols developed in our laboratory previously.
Description
Thesis (S.B.)--Massachusetts Institute of Technology, Dept. of Chemistry, February 2012. Cataloged from PDF version of thesis. Includes bibliographical references.
Date issued
2012Department
Massachusetts Institute of Technology. Department of ChemistryPublisher
Massachusetts Institute of Technology
Keywords
Chemistry.