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Kripa K. Varanasi. Damak, Maher, Ph. D. Massachusetts Institute of Technology Massachusetts Institute of Technology. Department of Mechanical Engineering. Massachusetts Institute of Technology. Department of Mechanical Engineering 2016-03-25T13:37:29Z 2016-03-25T13:37:29Z 2015 2015 http://hdl.handle.net/1721.1/101814 941275816 Thesis: S.M., Massachusetts Institute of Technology, Department of Mechanical Engineering, 2015. Cataloged from PDF version of thesis. Includes bibliographical references (pages 51-55). This thesis presents a study of the in-situ precipitation of polyelectrolytes during droplet impacts and its applications in enhancing the retention efficiency of sprays. Large amounts of agricultural sprays are wasted worldwide, due to the poor retention on hydrophobic plants. As the harmful effects of pesticides in particular are more and more pointed out, there is an increasing pressure to reduce their use and make their spraying more efficient. Current solutions, mainly based on surfactants, all have limitations. Here, we present a novel idea based on the modification of the surface of the plant. By precipitating opposite polyelectrolytes, in-situ, we create sparse pinning sites that pin the contact lines of the impacting droplets from the spray and prevent them from bouncing off. We first study the behavior of the impact of two droplets containing oppositely charged polyelectrolytes on a hydrophobic surface. We then study the precipitation process of two polyelectrolytes and develop a model that predicts the outcome of a double drop impact. Finally, we show the macroscopic applications of this study, by using simultaneous spraying. Simultaneously spraying dilute opposite polyelectrolytes on a superhydrophobic surface leads to a large increase in the liquid retention and the coverage of the surface. The behavior has been shown to hold for different polyelectrolytes and surfaces, making this method suitable for a range of applications. by Maher Damak. S.M. 55 pages eng Massachusetts Institute of Technology M.I.T. theses are protected by copyright. They may be viewed from this source for any purpose, but reproduction or distribution in any format is prohibited without written permission. See provided URL for inquiries about permission. http://dspace.mit.edu/handle/1721.1/7582 Mechanical Engineering. Droplet deposition on hydrophobic surfaces for agricultural sprays Thesis application/pdf Publication unknown unknown <Publication xmlns="https://www.openaire.eu/cerif-profile/1.1/" id="6951e156-3666-46ab-8d8f-6a94218104e2"> <Type xmlns="https://www.openaire.eu/cerif-profile/vocab/COAR_Publication_Types">http://purl.org/coar/resource_type/c_1843</Type> <Language>eng</Language> <Title>Droplet deposition on hydrophobic surfaces for agricultural sprays</Title> <PublishedIn> <Publication> </Publication> </PublishedIn> <PublicationDate>2015</PublicationDate> <Authors> <Author> <DisplayName>Damak, Maher, Ph. D. Massachusetts Institute of Technology</DisplayName> <Affiliation> <OrgUnit> </OrgUnit> </Affiliation> </Author> </Authors> <Editors> </Editors> <Publishers> <Publisher> <DisplayName>Massachusetts Institute of Technology</DisplayName> <OrgUnit /> </Publisher> </Publishers> <License>http://dspace.mit.edu/handle/1721.1/7582</License> <Keyword>Mechanical Engineering.</Keyword> <Abstract>This thesis presents a study of the in-situ precipitation of polyelectrolytes during droplet impacts and its applications in enhancing the retention efficiency of sprays. Large amounts of agricultural sprays are wasted worldwide, due to the poor retention on hydrophobic plants. As the harmful effects of pesticides in particular are more and more pointed out, there is an increasing pressure to reduce their use and make their spraying more efficient. Current solutions, mainly based on surfactants, all have limitations. Here, we present a novel idea based on the modification of the surface of the plant. By precipitating opposite polyelectrolytes, in-situ, we create sparse pinning sites that pin the contact lines of the impacting droplets from the spray and prevent them from bouncing off. We first study the behavior of the impact of two droplets containing oppositely charged polyelectrolytes on a hydrophobic surface. We then study the precipitation process of two polyelectrolytes and develop a model that predicts the outcome of a double drop impact. Finally, we show the macroscopic applications of this study, by using simultaneous spraying. Simultaneously spraying dilute opposite polyelectrolytes on a superhydrophobic surface leads to a large increase in the liquid retention and the coverage of the surface. The behavior has been shown to hold for different polyelectrolytes and surfaces, making this method suitable for a range of applications.</Abstract> <Access xmlns="http://purl.org/coar/access_right" > </Access> </Publication>