<?xml version="1.0" encoding="UTF-8"?><?xml-stylesheet type="text/xsl" href="static/style.xsl"?><OAI-PMH xmlns="http://www.openarchives.org/OAI/2.0/" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:schemaLocation="http://www.openarchives.org/OAI/2.0/ http://www.openarchives.org/OAI/2.0/OAI-PMH.xsd"><responseDate>2026-09-19T19:50:01Z</responseDate><request verb="GetRecord" identifier="oai:dspace.mit.edu:1721.1/104157" metadataPrefix="dim">https://dspace.mit.edu/server/oai/request</request><GetRecord><record><header><identifier>oai:dspace.mit.edu:1721.1/104157</identifier><datestamp>2026-06-06T01:04:51Z</datestamp><setSpec>com_1721.1_7582</setSpec><setSpec>com_1721.1_7581</setSpec><setSpec>col_1721.1_131022</setSpec><setSpec>col_1721.1_131023</setSpec></header><metadata><dim:dim xmlns:dim="http://www.dspace.org/xmlns/dspace/dim" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns:doc="http://www.lyncode.com/xoai" xsi:schemaLocation="http://www.dspace.org/xmlns/dspace/dim http://www.dspace.org/schema/dim.xsd">
   <dim:field mdschema="dc" element="contributor" qualifier="advisor" lang="en_US">Ruben Juanes.</dim:field>
   <dim:field mdschema="dc" element="contributor" qualifier="author" lang="en_US">Scandella, Benjamin P. (Benjamin Paul)</dim:field>
   <dim:field mdschema="dc" element="contributor" qualifier="other" lang="en_US">Massachusetts Institute of Technology. Department of Civil and Environmental Engineering.</dim:field>
   <dim:field mdschema="dc" element="contributor" qualifier="department">Massachusetts Institute of Technology. Department of Civil and Environmental Engineering</dim:field>
   <dim:field mdschema="dc" element="date" qualifier="accessioned">2016-09-13T18:11:09Z</dim:field>
   <dim:field mdschema="dc" element="date" qualifier="available">2016-09-13T18:11:09Z</dim:field>
   <dim:field mdschema="dc" element="date" qualifier="copyright" lang="en_US">2016</dim:field>
   <dim:field mdschema="dc" element="date" qualifier="issued" lang="en_US">2016</dim:field>
   <dim:field mdschema="dc" element="identifier" qualifier="uri">http://hdl.handle.net/1721.1/104157</dim:field>
   <dim:field mdschema="dc" element="identifier" qualifier="oclc" lang="en_US">958280487</dim:field>
   <dim:field mdschema="dc" element="description" lang="en_US">Thesis: Ph. D., Massachusetts Institute of Technology, Department of Civil and Environmental Engineering, 2016.</dim:field>
   <dim:field mdschema="dc" element="description" lang="en_US">This electronic version was submitted by the student author.  The certified thesis is available in the Institute Archives and Special Collections.</dim:field>
   <dim:field mdschema="dc" element="description" lang="en_US">Cataloged from student-submitted PDF version of thesis.</dim:field>
   <dim:field mdschema="dc" element="description" lang="en_US">Includes bibliographical references (pages 130-140).</dim:field>
   <dim:field mdschema="dc" element="description" qualifier="abstract" lang="en_US">Methane is a potent greenhouse gas, and natural sources to the atmosphere include inland waterways and shallow oceans. However, the magnitude of these emissions and their potential for feedbacks with climate change remain poorly constrained. In many settings the majority of atmospheric methane emissions is delivered by bubbles, and the spatiotemporal heterogeneity of ebullition makes measurement challenging and impacts bubble dissolution and atmospheric emissions. In this thesis, we present an analysis of both the episodicity and spatial structure of methane venting from soft sediments in a eutrophic lake over a range of spatial scales, from 1 cm to 20 m, and using a combination of field observations and laboratory experiments. Field-scale measurements of ebullition were acquired at the bottom of Upper Mystic Lake, MA, USA, using a high-resolution multibeam sonar during multiple deployments over a 9-month period. The sonar was calibrated to estimate the gas flow rates throughout a 330 m2 lateral observation area with resolution of 0.5 m. The results confirm that ebullition is strongly episodic, with distinct regimes of high- and low-flux largely controlled by changes in hydrostatic pressure. Statistical analysis shows that the spatial pattern of ebullition becomes homogeneous at the sonar's resolution over timescales of hours (for high-flux periods) or days (for low-flux periods), demonstrating that meter-scale methane vents are ephemeral rather than persistent. Laboratory-scale measurements were made in a controlled incubation of reconstituted sediments from the same field site. Image analysis of the 0.14 m2 observation area allowed identification of individual bubble outlets and resolved their location to ~ 1 cm. While ebullition events were typically concentrated in bursts lasting ~ 2 min, some major outlets showed persistent activity over the scale of days and even months. This persistence was surprising given the ephemerality of spatial structure at the field-scale. It suggests that, at the centimeter scale, conduits are re-used as a result of a drop in tensile strength due to deformation of sediments by the rising bubbles. By combining novel measurement techniques at different scales, we elucidate the mechanisms governing bubble growth and mobility, thereby supporting estimates of global methane fluxes from lakes and how their magnitude may vary with climate change.</dim:field>
   <dim:field mdschema="dc" element="description" qualifier="statementofresponsibility" lang="en_US">by Benjamin Paul Scandella.</dim:field>
   <dim:field mdschema="dc" element="description" qualifier="degree" lang="en_US">Ph.D.</dim:field>
   <dim:field mdschema="dc" element="format" qualifier="extent" lang="en_US">140 pages</dim:field>
   <dim:field mdschema="dc" element="language" qualifier="iso" lang="en_US">eng</dim:field>
   <dim:field mdschema="dc" element="publisher" lang="en_US">Massachusetts Institute of Technology</dim:field>
   <dim:field mdschema="dc" element="rights" lang="en_US">M.I.T. theses are protected by copyright. They may be viewed from this source for any purpose, but reproduction or distribution in any format is prohibited without written permission. See provided URL for inquiries about permission.</dim:field>
   <dim:field mdschema="dc" element="rights" qualifier="uri" lang="en_US">http://dspace.mit.edu/handle/1721.1/7582</dim:field>
   <dim:field mdschema="dc" element="subject" lang="en_US">Civil and Environmental Engineering.</dim:field>
   <dim:field mdschema="dc" element="title" lang="en_US">Spatiotemporal variability of methane ebullition from lake sediments</dim:field>
   <dim:field mdschema="dc" element="type" lang="en_US">Thesis</dim:field>
   <dim:field mdschema="dc" element="format" qualifier="mimetype">application/pdf</dim:field>
   <dim:field mdschema="dspace" element="authorsordered">false</dim:field>
   <dim:field mdschema="dspace" element="entity" qualifier="type">Publication</dim:field>
   <dim:field mdschema="others" element="access-status">unknown</dim:field>
   <dim:field mdschema="others" element="access-status">unknown</dim:field>
   <dim:field mdschema="cerif" element="openaire" authority="" confidence="-1">&lt;Publication xmlns="https://www.openaire.eu/cerif-profile/1.1/" id="403c635f-7efc-43b9-987e-97e7ec4e9573">
	&lt;Type xmlns="https://www.openaire.eu/cerif-profile/vocab/COAR_Publication_Types">http://purl.org/coar/resource_type/c_1843&lt;/Type>
	&lt;Language>eng&lt;/Language>
   	&lt;Title>Spatiotemporal variability of methane ebullition from lake sediments&lt;/Title>
   	&lt;PublishedIn>
    	&lt;Publication>
      	&lt;/Publication>
   	&lt;/PublishedIn>
   	&lt;PublicationDate>2016&lt;/PublicationDate>
   	&lt;Authors>
      	&lt;Author>
        	&lt;DisplayName>Scandella, Benjamin P. (Benjamin Paul)&lt;/DisplayName>
         	&lt;Affiliation>
         		&lt;OrgUnit>
         		&lt;/OrgUnit>
         	&lt;/Affiliation>
      	&lt;/Author>
	&lt;/Authors>
   	&lt;Editors>
	&lt;/Editors>
    &lt;Publishers>
        &lt;Publisher>
            &lt;DisplayName>Massachusetts Institute of Technology&lt;/DisplayName>
            &lt;OrgUnit />
        &lt;/Publisher>
    &lt;/Publishers>
    &lt;License>http://dspace.mit.edu/handle/1721.1/7582&lt;/License>
    &lt;Keyword>Civil and Environmental Engineering.&lt;/Keyword>
   	&lt;Abstract>Methane is a potent greenhouse gas, and natural sources to the atmosphere include inland waterways and shallow oceans. However, the magnitude of these emissions and their potential for feedbacks with climate change remain poorly constrained. In many settings the majority of atmospheric methane emissions is delivered by bubbles, and the spatiotemporal heterogeneity of ebullition makes measurement challenging and impacts bubble dissolution and atmospheric emissions. In this thesis, we present an analysis of both the episodicity and spatial structure of methane venting from soft sediments in a eutrophic lake over a range of spatial scales, from 1 cm to 20 m, and using a combination of field observations and laboratory experiments. Field-scale measurements of ebullition were acquired at the bottom of Upper Mystic Lake, MA, USA, using a high-resolution multibeam sonar during multiple deployments over a 9-month period. The sonar was calibrated to estimate the gas flow rates throughout a 330 m2 lateral observation area with resolution of 0.5 m. The results confirm that ebullition is strongly episodic, with distinct regimes of high- and low-flux largely controlled by changes in hydrostatic pressure. Statistical analysis shows that the spatial pattern of ebullition becomes homogeneous at the sonar&amp;apos;s resolution over timescales of hours (for high-flux periods) or days (for low-flux periods), demonstrating that meter-scale methane vents are ephemeral rather than persistent. Laboratory-scale measurements were made in a controlled incubation of reconstituted sediments from the same field site. Image analysis of the 0.14 m2 observation area allowed identification of individual bubble outlets and resolved their location to ~ 1 cm. While ebullition events were typically concentrated in bursts lasting ~ 2 min, some major outlets showed persistent activity over the scale of days and even months. This persistence was surprising given the ephemerality of spatial structure at the field-scale. It suggests that, at the centimeter scale, conduits are re-used as a result of a drop in tensile strength due to deformation of sediments by the rising bubbles. By combining novel measurement techniques at different scales, we elucidate the mechanisms governing bubble growth and mobility, thereby supporting estimates of global methane fluxes from lakes and how their magnitude may vary with climate change.&lt;/Abstract>
	&lt;Access xmlns="http://purl.org/coar/access_right" 
    >
    &lt;/Access>
&lt;/Publication>
</dim:field>
</dim:dim>
</metadata></record></GetRecord></OAI-PMH>