<?xml version="1.0" encoding="UTF-8"?><?xml-stylesheet type="text/xsl" href="static/style.xsl"?><OAI-PMH xmlns="http://www.openarchives.org/OAI/2.0/" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:schemaLocation="http://www.openarchives.org/OAI/2.0/ http://www.openarchives.org/OAI/2.0/OAI-PMH.xsd"><responseDate>2026-09-20T15:56:03Z</responseDate><request verb="GetRecord" identifier="oai:dspace.mit.edu:1721.1/105594" metadataPrefix="dim">https://dspace.mit.edu/server/oai/request</request><GetRecord><record><header><identifier>oai:dspace.mit.edu:1721.1/105594</identifier><datestamp>2022-01-13T07:54:07Z</datestamp><setSpec>com_1721.1_7582</setSpec><setSpec>com_1721.1_7581</setSpec><setSpec>col_1721.1_131024</setSpec></header><metadata><dim:dim xmlns:dim="http://www.dspace.org/xmlns/dspace/dim" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns:doc="http://www.lyncode.com/xoai" xsi:schemaLocation="http://www.dspace.org/xmlns/dspace/dim http://www.dspace.org/schema/dim.xsd">
   <dim:field mdschema="dc" element="contributor" qualifier="advisor" lang="en_US">Marin Soljač̌ić́.</dim:field>
   <dim:field mdschema="dc" element="contributor" qualifier="author" lang="en_US">Leal Machado, Francisco</dim:field>
   <dim:field mdschema="dc" element="contributor" qualifier="other" lang="en_US">Massachusetts Institute of Technology. Department of Physics.</dim:field>
   <dim:field mdschema="dc" element="contributor" qualifier="department">Massachusetts Institute of Technology. Department of Physics</dim:field>
   <dim:field mdschema="dc" element="date" qualifier="accessioned">2016-12-05T19:54:09Z</dim:field>
   <dim:field mdschema="dc" element="date" qualifier="available">2016-12-05T19:54:09Z</dim:field>
   <dim:field mdschema="dc" element="date" qualifier="copyright" lang="en_US">2016</dim:field>
   <dim:field mdschema="dc" element="date" qualifier="issued" lang="en_US">2016</dim:field>
   <dim:field mdschema="dc" element="identifier" qualifier="uri">http://hdl.handle.net/1721.1/105594</dim:field>
   <dim:field mdschema="dc" element="identifier" qualifier="oclc" lang="en_US">961269848</dim:field>
   <dim:field mdschema="dc" element="description" lang="en_US">Thesis: S.B., Massachusetts Institute of Technology, Department of Physics, 2016.</dim:field>
   <dim:field mdschema="dc" element="description" lang="en_US">Cataloged from PDF version of thesis.</dim:field>
   <dim:field mdschema="dc" element="description" lang="en_US">Includes bibliographical references (pages 69-73).</dim:field>
   <dim:field mdschema="dc" element="description" qualifier="abstract" lang="en_US">The discovery of orbital angular momentum (OAM) sustaining modes established a new degree of freedom by which to control not only the flow of light but also its interaction with matter. However, OAM sustaining modes have yet to be used to control the quantum dynamics of an electron in an atom or molecule due to the large length scale discrepancy between the wavelength of light and the size of the electron's orbital. In this work, we analyze the interaction between OAM carrying polariton vortex modes (for plasmon and phonon polaritons) and a hydrogen atom, and show that these modes can be used to engineer new selection rules in electronic transitions. Moreover, we show that these selection rules are robust to the displacement of the electronic system away from the vortex center. Perhaps more surprisingly, we find how displacement can be used favourably to tune which absorption process is dominant. Our findings are best suited to vortex modes that can be created in graphene, monolayer conductors, hBN, thin polar dielectrics, and many other polariton-sustaining thin materials. Another platform for observing these effects could be quantum dots interfaced with surface plasmons in-conventional metals.</dim:field>
   <dim:field mdschema="dc" element="description" qualifier="statementofresponsibility" lang="en_US">by Francisco Leal Machado.</dim:field>
   <dim:field mdschema="dc" element="description" qualifier="degree" lang="en_US">S.B.</dim:field>
   <dim:field mdschema="dc" element="format" qualifier="extent" lang="en_US">73 pages</dim:field>
   <dim:field mdschema="dc" element="language" qualifier="iso" lang="en_US">eng</dim:field>
   <dim:field mdschema="dc" element="publisher" lang="en_US">Massachusetts Institute of Technology</dim:field>
   <dim:field mdschema="dc" element="rights" lang="en_US">M.I.T. theses are protected by copyright. They may be viewed from this source for any purpose, but reproduction or distribution in any format is prohibited without written permission. See provided URL for inquiries about permission.</dim:field>
   <dim:field mdschema="dc" element="rights" qualifier="uri" lang="en_US">http://dspace.mit.edu/handle/1721.1/7582</dim:field>
   <dim:field mdschema="dc" element="subject" lang="en_US">Physics.</dim:field>
   <dim:field mdschema="dc" element="title" lang="en_US">Using 2D vortex plasmons/phonon polaritons to control electronic selection rules</dim:field>
   <dim:field mdschema="dc" element="title" qualifier="alternative" lang="en_US">Using 2-dimensional plasmons/phonon polaritons to control electronic selection rules</dim:field>
   <dim:field mdschema="dc" element="title" qualifier="alternative" lang="en_US">Using two-dimensional vortex plasmons/phonon polaritons to control electronic selection rules</dim:field>
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   	&lt;Title>Using 2D vortex plasmons/phonon polaritons to control electronic selection rules&lt;/Title>
   	&lt;Subtitle>Using 2-dimensional plasmons/phonon polaritons to control electronic selection rules&lt;/Subtitle>
   	&lt;Subtitle>Using two-dimensional vortex plasmons/phonon polaritons to control electronic selection rules&lt;/Subtitle>
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   	&lt;PublicationDate>2016&lt;/PublicationDate>
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        	&lt;DisplayName>Leal Machado, Francisco&lt;/DisplayName>
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            &lt;DisplayName>Massachusetts Institute of Technology&lt;/DisplayName>
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    &lt;Keyword>Physics.&lt;/Keyword>
   	&lt;Abstract>The discovery of orbital angular momentum (OAM) sustaining modes established a new degree of freedom by which to control not only the flow of light but also its interaction with matter. However, OAM sustaining modes have yet to be used to control the quantum dynamics of an electron in an atom or molecule due to the large length scale discrepancy between the wavelength of light and the size of the electron&amp;apos;s orbital. In this work, we analyze the interaction between OAM carrying polariton vortex modes (for plasmon and phonon polaritons) and a hydrogen atom, and show that these modes can be used to engineer new selection rules in electronic transitions. Moreover, we show that these selection rules are robust to the displacement of the electronic system away from the vortex center. Perhaps more surprisingly, we find how displacement can be used favourably to tune which absorption process is dominant. Our findings are best suited to vortex modes that can be created in graphene, monolayer conductors, hBN, thin polar dielectrics, and many other polariton-sustaining thin materials. Another platform for observing these effects could be quantum dots interfaced with surface plasmons in-conventional metals.&lt;/Abstract>
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