<?xml version="1.0" encoding="UTF-8"?><?xml-stylesheet type="text/xsl" href="static/style.xsl"?><OAI-PMH xmlns="http://www.openarchives.org/OAI/2.0/" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:schemaLocation="http://www.openarchives.org/OAI/2.0/ http://www.openarchives.org/OAI/2.0/OAI-PMH.xsd"><responseDate>2026-09-19T18:50:51Z</responseDate><request verb="GetRecord" identifier="oai:dspace.mit.edu:1721.1/111256" metadataPrefix="dim">https://dspace.mit.edu/server/oai/request</request><GetRecord><record><header><identifier>oai:dspace.mit.edu:1721.1/111256</identifier><datestamp>2026-06-16T18:53:48Z</datestamp><setSpec>com_1721.1_7582</setSpec><setSpec>com_1721.1_7581</setSpec><setSpec>col_1721.1_131022</setSpec></header><metadata><dim:dim xmlns:dim="http://www.dspace.org/xmlns/dspace/dim" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns:doc="http://www.lyncode.com/xoai" xsi:schemaLocation="http://www.dspace.org/xmlns/dspace/dim http://www.dspace.org/schema/dim.xsd">
   <dim:field mdschema="dc" element="contributor" qualifier="advisor" lang="en_US">Jesús A. del Alamo.</dim:field>
   <dim:field mdschema="dc" element="contributor" qualifier="author" lang="en_US">Zhao, Xin, Ph. D. Massachusetts Institute of Technology</dim:field>
   <dim:field mdschema="dc" element="contributor" qualifier="other" lang="en_US">Massachusetts Institute of Technology. Department of Materials Science and Engineering.</dim:field>
   <dim:field mdschema="dc" element="contributor" qualifier="department">Massachusetts Institute of Technology. Department of Materials Science and Engineering</dim:field>
   <dim:field mdschema="dc" element="date" qualifier="accessioned">2017-09-15T14:21:33Z</dim:field>
   <dim:field mdschema="dc" element="date" qualifier="available">2017-09-15T14:21:33Z</dim:field>
   <dim:field mdschema="dc" element="date" qualifier="copyright" lang="en_US">2017</dim:field>
   <dim:field mdschema="dc" element="date" qualifier="issued" lang="en_US">2017</dim:field>
   <dim:field mdschema="dc" element="identifier" qualifier="uri">http://hdl.handle.net/1721.1/111256</dim:field>
   <dim:field mdschema="dc" element="identifier" qualifier="oclc" lang="en_US">1003290886</dim:field>
   <dim:field mdschema="dc" element="description" lang="en_US">Thesis: Ph. D., Massachusetts Institute of Technology, Department of Materials Science and Engineering, 2017.</dim:field>
   <dim:field mdschema="dc" element="description" lang="en_US">This electronic version was submitted by the student author.  The certified thesis is available in the Institute Archives and Special Collections.</dim:field>
   <dim:field mdschema="dc" element="description" lang="en_US">Cataloged from student-submitted PDF version of thesis.</dim:field>
   <dim:field mdschema="dc" element="description" lang="en_US">Includes bibliographical references (pages 156-166).</dim:field>
   <dim:field mdschema="dc" element="description" qualifier="abstract" lang="en_US">Combining the superior carrier transport properties and flexible band structure engineering from III-V materials and ultimate scalability of vertical nanowire (VNW) device architecture, III-V VNW transistors are promising to extend Moore's law further than any other device technology. In this thesis, III-V VNW transistor technology has been pioneered via a top down approach for logic applications in future ultra-low power systems. Process flow and critical modules for sub-10 nm VNW transistors are developed from scratch. A novel dry etch technique based on BCl₃/SiCl₄/Ar chemistry for fabricating sub-20 nm III-V nanostructures with smooth, vertical sidewall and high aspect ratio (> 10) is developed. Digital etch (DE) is shown to mitigate the dry etch damage and reduce NW diameter below 10 nm in a controllable fashion while preserving the sidewall roughness and NW shape. Top-down InGaAs VNW MOSFET is demonstrated for the first time. Record Ion of 224 μA/μm is obtained at Ioff = 100 nA/μm with Vdd = 0.5 V in third generation devices. With novel solvent-based, switching characteristics are observed in devices with diameter as small as 14 nm. The impact of the intrinsic source/drain asymmetry on the device electrical characteristics is studied in detail, highlighting the importance of uniform NW diameter. The first experimental demonstration of III-V VNW TFETs with an InGaAs/InAs heterojunction fabricated by a top-down approach is introduced. Second generation TFETs demonstrate sub-thermal subthreshold characteristics over two orders of magnitude of current and a record high I60 in any experimental TFETs for Vds &lt; 1 V at the time of device fabrication. The comparison of two generations of TFETs confirms oxide/semiconductor interface trapassisted tunneling as the source of significant temperature dependence in the first device generation. Detailed analysis on the conductance-voltage characteristics on both generations of devices reveal a 100-120 mV/dec steepness of Urbach tails in the VNW TFETs.</dim:field>
   <dim:field mdschema="dc" element="description" qualifier="statementofresponsibility" lang="en_US">by Xin Zhao.</dim:field>
   <dim:field mdschema="dc" element="description" qualifier="degree" lang="en_US">Ph.D.</dim:field>
   <dim:field mdschema="dc" element="format" qualifier="extent" lang="en_US">166 pages</dim:field>
   <dim:field mdschema="dc" element="language" qualifier="iso" lang="en_US">eng</dim:field>
   <dim:field mdschema="dc" element="publisher" lang="en_US">Massachusetts Institute of Technology</dim:field>
   <dim:field mdschema="dc" element="rights" lang="en_US">MIT theses are protected by copyright. They may be viewed, downloaded, or printed from this source but further reproduction or distribution in any format is prohibited without written permission.</dim:field>
   <dim:field mdschema="dc" element="rights" qualifier="uri" lang="en_US">http://dspace.mit.edu/handle/1721.1/7582</dim:field>
   <dim:field mdschema="dc" element="subject" lang="en_US">Materials Science and Engineering.</dim:field>
   <dim:field mdschema="dc" element="title" lang="en_US">III-V vertical nanowire transistor for ultra-low power applications</dim:field>
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   	&lt;Title>III-V vertical nanowire transistor for ultra-low power applications&lt;/Title>
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   	&lt;PublicationDate>2017&lt;/PublicationDate>
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        	&lt;DisplayName>Zhao, Xin, Ph. D. Massachusetts Institute of Technology&lt;/DisplayName>
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    &lt;Keyword>Materials Science and Engineering.&lt;/Keyword>
   	&lt;Abstract>Combining the superior carrier transport properties and flexible band structure engineering from III-V materials and ultimate scalability of vertical nanowire (VNW) device architecture, III-V VNW transistors are promising to extend Moore&amp;apos;s law further than any other device technology. In this thesis, III-V VNW transistor technology has been pioneered via a top down approach for logic applications in future ultra-low power systems. Process flow and critical modules for sub-10 nm VNW transistors are developed from scratch. A novel dry etch technique based on BCl₃/SiCl₄/Ar chemistry for fabricating sub-20 nm III-V nanostructures with smooth, vertical sidewall and high aspect ratio (&amp;gt; 10) is developed. Digital etch (DE) is shown to mitigate the dry etch damage and reduce NW diameter below 10 nm in a controllable fashion while preserving the sidewall roughness and NW shape. Top-down InGaAs VNW MOSFET is demonstrated for the first time. Record Ion of 224 μA/μm is obtained at Ioff = 100 nA/μm with Vdd = 0.5 V in third generation devices. With novel solvent-based, switching characteristics are observed in devices with diameter as small as 14 nm. The impact of the intrinsic source/drain asymmetry on the device electrical characteristics is studied in detail, highlighting the importance of uniform NW diameter. The first experimental demonstration of III-V VNW TFETs with an InGaAs/InAs heterojunction fabricated by a top-down approach is introduced. Second generation TFETs demonstrate sub-thermal subthreshold characteristics over two orders of magnitude of current and a record high I60 in any experimental TFETs for Vds &amp;lt; 1 V at the time of device fabrication. The comparison of two generations of TFETs confirms oxide/semiconductor interface trapassisted tunneling as the source of significant temperature dependence in the first device generation. Detailed analysis on the conductance-voltage characteristics on both generations of devices reveal a 100-120 mV/dec steepness of Urbach tails in the VNW TFETs.&lt;/Abstract>
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