2026-09-19T19:12:13Zhttps://dspace.mit.edu/server/oai/requestoai:dspace.mit.edu:1721.1/1117242022-01-13T07:54:05Zcom_1721.1_7582com_1721.1_7581col_1721.1_131023
Betar M. Gallant.
Li, Yuanda
Massachusetts Institute of Technology. Department of Mechanical Engineering.
Massachusetts Institute of Technology. Department of Mechanical Engineering
2017-10-04T15:05:34Z
2017-10-04T15:05:34Z
2017
2017
http://hdl.handle.net/1721.1/111724
1004236835
Thesis: S.M., Massachusetts Institute of Technology, Department of Mechanical Engineering, 2017.
Cataloged from PDF version of thesis.
Includes bibliographical references (pages 57-60).
The demand for technological advancement of greenhouse gas conversion and mitigation strategies is ever increasing. In this thesis, a non-aqueous electrochemical platform with metal lithium (Li) as the anode and carbon as the cathode has been developed to convert the most potent greenhouse gas, sulfur hexafluoride (SF 6), into benign solids Li2S and LiF under room temperature conditions at an electrode - electrolyte interface. Galvanostatic discharge demonstrated that the reaction between Li and SF 6 is capable of delivering modest cell voltages up to - 2.4 V vs. Li/Lie and capacities up to ~3800 mAh/gc. The electrochemical reaction between Li and SF6 in two different battery solvents has been characterized with a suite of solid and liquid phase analyses, which showed the reaction to be an 8 - electron transfer process with high Coulombic efficiency. Rotating disk electrode studies were also employed to demonstrate that the overpotential of this system is intrinsically governed by kinetics. This work demonstrates a non-aqueous system capable of both reducing a fluorinated gas, SF6 under room temperature conditions at an electrode surface, and acting as a primary battery based on halogen ligand chemistry.
by Yuanda Li.
S.M.
60 pages
eng
Massachusetts Institute of Technology
MIT theses are protected by copyright. They may be viewed, downloaded, or printed from this source but further reproduction or distribution in any format is prohibited without written permission.
http://dspace.mit.edu/handle/1721.1/7582
Mechanical Engineering.
Electrochemical conversion of a fluorinated greenhouse gas using a lithium battery configuration
Thesis
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<Abstract>The demand for technological advancement of greenhouse gas conversion and mitigation strategies is ever increasing. In this thesis, a non-aqueous electrochemical platform with metal lithium (Li) as the anode and carbon as the cathode has been developed to convert the most potent greenhouse gas, sulfur hexafluoride (SF 6), into benign solids Li2S and LiF under room temperature conditions at an electrode - electrolyte interface. Galvanostatic discharge demonstrated that the reaction between Li and SF 6 is capable of delivering modest cell voltages up to - 2.4 V vs. Li/Lie and capacities up to ~3800 mAh/gc. The electrochemical reaction between Li and SF6 in two different battery solvents has been characterized with a suite of solid and liquid phase analyses, which showed the reaction to be an 8 - electron transfer process with high Coulombic efficiency. Rotating disk electrode studies were also employed to demonstrate that the overpotential of this system is intrinsically governed by kinetics. This work demonstrates a non-aqueous system capable of both reducing a fluorinated gas, SF6 under room temperature conditions at an electrode surface, and acting as a primary battery based on halogen ligand chemistry.</Abstract>
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