<?xml version="1.0" encoding="UTF-8"?><?xml-stylesheet type="text/xsl" href="static/style.xsl"?><OAI-PMH xmlns="http://www.openarchives.org/OAI/2.0/" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:schemaLocation="http://www.openarchives.org/OAI/2.0/ http://www.openarchives.org/OAI/2.0/OAI-PMH.xsd"><responseDate>2026-09-18T20:32:29Z</responseDate><request verb="GetRecord" identifier="oai:dspace.mit.edu:1721.1/152658" metadataPrefix="dim">https://dspace.mit.edu/server/oai/request</request><GetRecord><record><header><identifier>oai:dspace.mit.edu:1721.1/152658</identifier><datestamp>2023-11-03T03:28:49Z</datestamp><setSpec>com_1721.1_7582</setSpec><setSpec>com_1721.1_7581</setSpec><setSpec>col_1721.1_131022</setSpec></header><metadata><dim:dim xmlns:dim="http://www.dspace.org/xmlns/dspace/dim" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns:doc="http://www.lyncode.com/xoai" xsi:schemaLocation="http://www.dspace.org/xmlns/dspace/dim http://www.dspace.org/schema/dim.xsd">
   <dim:field mdschema="dc" element="contributor" qualifier="advisor">del Alamo, Jesús A.</dim:field>
   <dim:field mdschema="dc" element="contributor" qualifier="advisor">Antoniadis, Dimitri A.</dim:field>
   <dim:field mdschema="dc" element="contributor" qualifier="author">Kim, Taekyong</dim:field>
   <dim:field mdschema="dc" element="contributor" qualifier="department">Massachusetts Institute of Technology. Department of Electrical Engineering and Computer Science</dim:field>
   <dim:field mdschema="dc" element="date" qualifier="accessioned">2023-11-02T20:06:26Z</dim:field>
   <dim:field mdschema="dc" element="date" qualifier="available">2023-11-02T20:06:26Z</dim:field>
   <dim:field mdschema="dc" element="date" qualifier="issued">2023-09</dim:field>
   <dim:field mdschema="dc" element="date" qualifier="submitted">2023-09-21T14:26:28.571Z</dim:field>
   <dim:field mdschema="dc" element="identifier" qualifier="uri">https://hdl.handle.net/1721.1/152658</dim:field>
   <dim:field mdschema="dc" element="identifier" qualifier="orcid">https://orcid.org/0000-0001-8054-6430</dim:field>
   <dim:field mdschema="dc" element="description" qualifier="abstract">Ferroelectric Hf₀.₅Zr₀.₅O₂ (FE-HZO) has breathed new life into the field of ferroelectric research, boasting exceptional physical properties, such as compatibility with existing semiconductor processes, highly scalable thickness, and prominent FE properties. As a result, this intriguing material has gathered extensive attention for applications in ultra-scaled Si MOSFETs, memory devices, energy-efficient hardware for convolutional computation, and RF devices. However, despite intense research, there is still controversy about the FE switching dynamics, a crucial factor in designing ferroelectric device applications.&#xd;
&#xd;
This thesis pursues fundamental understanding of the switching dynamics in FE-HZO structures founded on accurate dynamic measurements with meticulous experimental design considerations. Towards this, low-parasitic FE-HZO structures have been fabricated and characterized over a broad range of frequencies using large-signal and small-signal analysis. In large-signal analysis, a Finite-Difference implementation of the Nucleation Limited Switching model (FD-NLS) is introduced, which accurately predicts the FE circuit dynamics across a wide range of time scales. Additionally, a thorough analysis of the imprint effect, a critical reliability issue in FE devices is provided. In small-signal analysis, a physically meaningful small-signal equivalent circuit model is developed that describes impedance measurements well over a full bias range and 7 orders of magnitude of frequency all the way into the GHz regime. Moreover, this work sheds light on the underlying physics of the circuit elements.&#xd;
&#xd;
The findings in this thesis will contribute to the design and modeling of diverse FE-HZO devices for a wide range of applications, adding valuable knowledge to the field of FE-HZO research.</dim:field>
   <dim:field mdschema="dc" element="description" qualifier="degree">Ph.D.</dim:field>
   <dim:field mdschema="dc" element="publisher">Massachusetts Institute of Technology</dim:field>
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   <dim:field mdschema="dc" element="title">Switching Dynamics in Ferroelectric Hf₀.₅Zr₀.₅O₂ Devices: Experiments and Models</dim:field>
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   	&lt;Title>Switching Dynamics in Ferroelectric Hf₀.₅Zr₀.₅O₂ Devices: Experiments and Models&lt;/Title>
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        	&lt;DisplayName>Kim, Taekyong&lt;/DisplayName>
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   	&lt;Abstract>Ferroelectric Hf₀.₅Zr₀.₅O₂ (FE-HZO) has breathed new life into the field of ferroelectric research, boasting exceptional physical properties, such as compatibility with existing semiconductor processes, highly scalable thickness, and prominent FE properties. As a result, this intriguing material has gathered extensive attention for applications in ultra-scaled Si MOSFETs, memory devices, energy-efficient hardware for convolutional computation, and RF devices. However, despite intense research, there is still controversy about the FE switching dynamics, a crucial factor in designing ferroelectric device applications.&#xd;
&#xd;
This thesis pursues fundamental understanding of the switching dynamics in FE-HZO structures founded on accurate dynamic measurements with meticulous experimental design considerations. Towards this, low-parasitic FE-HZO structures have been fabricated and characterized over a broad range of frequencies using large-signal and small-signal analysis. In large-signal analysis, a Finite-Difference implementation of the Nucleation Limited Switching model (FD-NLS) is introduced, which accurately predicts the FE circuit dynamics across a wide range of time scales. Additionally, a thorough analysis of the imprint effect, a critical reliability issue in FE devices is provided. In small-signal analysis, a physically meaningful small-signal equivalent circuit model is developed that describes impedance measurements well over a full bias range and 7 orders of magnitude of frequency all the way into the GHz regime. Moreover, this work sheds light on the underlying physics of the circuit elements.&#xd;
&#xd;
The findings in this thesis will contribute to the design and modeling of diverse FE-HZO devices for a wide range of applications, adding valuable knowledge to the field of FE-HZO research.&lt;/Abstract>
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