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W. Craig Carter. Bishop, Catherine M. (Catherine Mary), 1975- Massachusetts Institute of Technology. Dept. of Materials Science and Engineering. Massachusetts Institute of Technology. Department of Materials Science and Engineering 2006-03-24T18:07:27Z 2006-03-24T18:07:27Z 2003 2003 http://hdl.handle.net/1721.1/29968 54763852 Thesis (Ph. D.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, 2003. Includes bibliographical references (leaves 145-155). A continuum thermodynamic model is developed for the treatment of interfaces in materials. This phase-field model includes energetic contributions from chemical, structural and electrostatic effects. A small parameter set is introduced in the model. These parameters should be adjusted based on the relation of equilibrated phase-field structures to atomistic simulations and experimental observations. To compare the continuum fields to discrete data sets, coarse-graining methods are proposed. Two methods of measuring local atomic structure are developed, one based on Voronoi tessellations and the other based on bond-angle distribution functions. A coarse-graining method based on volume averaging over Voronoi tessellations is employed to continuize both structure and composition information. These fields give insight into the local atomic environment that is necessary for devising continuum models. The stability of intergranular films in CaO-doped Si₃N₄ is examined. A modified associate model that incorporates bulk-thermodynamic Gibbs free energy functions and treats non-bulk equilibrium compositions is developed. Kinetic equations are derived to solve for the equilibrium fields. While the simulations do not reach equilibrium, some trends can be observed. Locally charged domains are kinetically stable near the film. Non-uniform calcium distributions in the doped films indicate that calcium is preferentially located near the film-grain interface. The structural width of the film can be tuned by altering appropriate model parameters. (cont.) Future avenues of research suggested by this thesis include: developing algorithms for measuring local structure and orientation in multi-component systems and devising atomistic simulations of intergranular pockets that couple experimental information with interatomic potentials. by Catherine M. Bishop. Ph.D. 155 leaves 5623325 bytes 9943528 bytes application/pdf application/pdf eng Massachusetts Institute of Technology M.I.T. theses are protected by copyright. They may be viewed from this source for any purpose, but reproduction or distribution in any format is prohibited without written permission. See provided URL for inquiries about permission. http://dspace.mit.edu/handle/1721.1/7582 Materials Science and Engineering. Continuum models for intergranular films in silicon nitride and comparison to atomistic simulations Thesis application/pdf Publication unknown unknown <Publication xmlns="https://www.openaire.eu/cerif-profile/1.1/" id="48967601-7de8-4f08-8808-61fce5fa1a3b"> <Type xmlns="https://www.openaire.eu/cerif-profile/vocab/COAR_Publication_Types">http://purl.org/coar/resource_type/c_1843</Type> <Language>eng</Language> <Title>Continuum models for intergranular films in silicon nitride and comparison to atomistic simulations</Title> <PublishedIn> <Publication> </Publication> </PublishedIn> <PublicationDate>2003</PublicationDate> <Authors> <Author> <DisplayName>Bishop, Catherine M. (Catherine Mary), 1975-</DisplayName> <Affiliation> <OrgUnit> </OrgUnit> </Affiliation> </Author> </Authors> <Editors> </Editors> <Publishers> <Publisher> <DisplayName>Massachusetts Institute of Technology</DisplayName> <OrgUnit /> </Publisher> </Publishers> <License>http://dspace.mit.edu/handle/1721.1/7582</License> <Keyword>Materials Science and Engineering.</Keyword> <Abstract>A continuum thermodynamic model is developed for the treatment of interfaces in materials. This phase-field model includes energetic contributions from chemical, structural and electrostatic effects. A small parameter set is introduced in the model. These parameters should be adjusted based on the relation of equilibrated phase-field structures to atomistic simulations and experimental observations. To compare the continuum fields to discrete data sets, coarse-graining methods are proposed. Two methods of measuring local atomic structure are developed, one based on Voronoi tessellations and the other based on bond-angle distribution functions. A coarse-graining method based on volume averaging over Voronoi tessellations is employed to continuize both structure and composition information. These fields give insight into the local atomic environment that is necessary for devising continuum models. The stability of intergranular films in CaO-doped Si₃N₄ is examined. A modified associate model that incorporates bulk-thermodynamic Gibbs free energy functions and treats non-bulk equilibrium compositions is developed. Kinetic equations are derived to solve for the equilibrium fields. While the simulations do not reach equilibrium, some trends can be observed. Locally charged domains are kinetically stable near the film. Non-uniform calcium distributions in the doped films indicate that calcium is preferentially located near the film-grain interface. The structural width of the film can be tuned by altering appropriate model parameters.</Abstract> <Abstract>(cont.) Future avenues of research suggested by this thesis include: developing algorithms for measuring local structure and orientation in multi-component systems and devising atomistic simulations of intergranular pockets that couple experimental information with interatomic potentials.</Abstract> <Access xmlns="http://purl.org/coar/access_right" > </Access> </Publication>