<?xml version="1.0" encoding="UTF-8"?><?xml-stylesheet type="text/xsl" href="static/style.xsl"?><OAI-PMH xmlns="http://www.openarchives.org/OAI/2.0/" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:schemaLocation="http://www.openarchives.org/OAI/2.0/ http://www.openarchives.org/OAI/2.0/OAI-PMH.xsd"><responseDate>2026-09-19T12:13:21Z</responseDate><request verb="GetRecord" identifier="oai:dspace.mit.edu:1721.1/61597" metadataPrefix="dim">https://dspace.mit.edu/server/oai/request</request><GetRecord><record><header><identifier>oai:dspace.mit.edu:1721.1/61597</identifier><datestamp>2022-01-13T07:54:36Z</datestamp><setSpec>com_1721.1_7582</setSpec><setSpec>com_1721.1_7581</setSpec><setSpec>col_1721.1_131022</setSpec></header><metadata><dim:dim xmlns:dim="http://www.dspace.org/xmlns/dspace/dim" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns:doc="http://www.lyncode.com/xoai" xsi:schemaLocation="http://www.dspace.org/xmlns/dspace/dim http://www.dspace.org/schema/dim.xsd">
   <dim:field mdschema="dc" element="contributor" qualifier="advisor" lang="en_US">Jung-Hoon Chun and Nannaji Saka.</dim:field>
   <dim:field mdschema="dc" element="contributor" qualifier="author" lang="en_US">Eusner, Thor</dim:field>
   <dim:field mdschema="dc" element="contributor" qualifier="other" lang="en_US">Massachusetts Institute of Technology. Dept. of Mechanical Engineering.</dim:field>
   <dim:field mdschema="dc" element="contributor" qualifier="department">Massachusetts Institute of Technology. Department of Mechanical Engineering</dim:field>
   <dim:field mdschema="dc" element="date" qualifier="accessioned">2011-03-07T15:20:56Z</dim:field>
   <dim:field mdschema="dc" element="date" qualifier="available">2011-03-07T15:20:56Z</dim:field>
   <dim:field mdschema="dc" element="date" qualifier="copyright" lang="en_US">2010</dim:field>
   <dim:field mdschema="dc" element="date" qualifier="issued" lang="en_US">2010</dim:field>
   <dim:field mdschema="dc" element="identifier" qualifier="uri">http://hdl.handle.net/1721.1/61597</dim:field>
   <dim:field mdschema="dc" element="identifier" qualifier="oclc" lang="en_US">704294343</dim:field>
   <dim:field mdschema="dc" element="description" lang="en_US">Thesis (Ph. D.)--Massachusetts Institute of Technology, Dept. of Mechanical Engineering, 2010.</dim:field>
   <dim:field mdschema="dc" element="description" lang="en_US">Cataloged from PDF version of thesis.</dim:field>
   <dim:field mdschema="dc" element="description" lang="en_US">Includes bibliographical references (p. 228-241).</dim:field>
   <dim:field mdschema="dc" element="description" qualifier="abstract" lang="en_US">In the fabrication of ultra-large-scale integrated (ULSI) semiconductor devices, the chemical-mechanical polishing (CMP) process is extensively employed. During the CMP process, undesirable scratches are produced on Cu interconnects both by the abrasive particles in the slurry and by the softer pad asperities. In order to meet the stringent demands of precision polishing, scratching must be mitigated or eliminated. This thesis presents scratching models by analytical contact mechanics, finite element analysis, and statistical methods. First, scratching due to hard, abrasive particles was modeled and expressions for the maximum and minimum scratch width and depth were determined. Second, scratching of a hard surface by a softer body, specifically the scratching of a Cu coating by a soft pad asperity, was modeled. It was first assumed that the asperity deforms linear elastically up to the onset of yielding. A Hertzian pressure distribution in contact with a coating, with and without friction, was modeled to determine the maximum contact pressure that can induce yielding in the coating. It was then assumed that the pad asperity deforms fully-plastically. A uniform pressure distribution in contact with a coating, with and without friction, was modeled to determine the maximum contact pressure required to induce yielding in the coating. The maximum pressure was then related to the pad asperity hardness for both contact pressure distributions. Finally, statistical asperity contact models were developed to relate the pad asperity radius of curvature to the type of asperity deformation, i.e. elastic at the onset of yielding or fully-plastic. As a result of these models, expressions that relate Cu coating scratching to the ratio of pad-to-coating hardness, coefficient of friction, and pad asperity radius of curvature were developed. The scratching by pad asperity models were validated by performing single and multi-asperity sliding experiments. The effects of pad hardness, pad asperity radius of curvature, and coefficient of friction were related to the frequency and severity of scratching.</dim:field>
   <dim:field mdschema="dc" element="description" qualifier="statementofresponsibility" lang="en_US">by Thor Eusner.</dim:field>
   <dim:field mdschema="dc" element="description" qualifier="degree" lang="en_US">Ph.D.</dim:field>
   <dim:field mdschema="dc" element="format" qualifier="extent" lang="en_US">241 p.</dim:field>
   <dim:field mdschema="dc" element="language" qualifier="iso" lang="en_US">eng</dim:field>
   <dim:field mdschema="dc" element="publisher" lang="en_US">Massachusetts Institute of Technology</dim:field>
   <dim:field mdschema="dc" element="rights" lang="en_US">M.I.T. theses are protected by 
copyright. They may be viewed from this source for any purpose, but 
reproduction or distribution in any format is prohibited without written 
permission. See provided URL for inquiries about permission.</dim:field>
   <dim:field mdschema="dc" element="rights" qualifier="uri" lang="en_US">http://dspace.mit.edu/handle/1721.1/7582</dim:field>
   <dim:field mdschema="dc" element="subject" lang="en_US">Mechanical Engineering.</dim:field>
   <dim:field mdschema="dc" element="title" lang="en_US">Multi-scale scratching in chemical-mechanical polishing</dim:field>
   <dim:field mdschema="dc" element="title" qualifier="alternative" lang="en_US">Multi-scale scratching in CMP</dim:field>
   <dim:field mdschema="dc" element="type" lang="en_US">Thesis</dim:field>
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	&lt;Language>eng&lt;/Language>
   	&lt;Title>Multi-scale scratching in chemical-mechanical polishing&lt;/Title>
   	&lt;Subtitle>Multi-scale scratching in CMP&lt;/Subtitle>
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    	&lt;Publication>
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   	&lt;PublicationDate>2010&lt;/PublicationDate>
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        	&lt;DisplayName>Eusner, Thor&lt;/DisplayName>
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            &lt;DisplayName>Massachusetts Institute of Technology&lt;/DisplayName>
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    &lt;License>http://dspace.mit.edu/handle/1721.1/7582&lt;/License>
    &lt;Keyword>Mechanical Engineering.&lt;/Keyword>
   	&lt;Abstract>In the fabrication of ultra-large-scale integrated (ULSI) semiconductor devices, the chemical-mechanical polishing (CMP) process is extensively employed. During the CMP process, undesirable scratches are produced on Cu interconnects both by the abrasive particles in the slurry and by the softer pad asperities. In order to meet the stringent demands of precision polishing, scratching must be mitigated or eliminated. This thesis presents scratching models by analytical contact mechanics, finite element analysis, and statistical methods. First, scratching due to hard, abrasive particles was modeled and expressions for the maximum and minimum scratch width and depth were determined. Second, scratching of a hard surface by a softer body, specifically the scratching of a Cu coating by a soft pad asperity, was modeled. It was first assumed that the asperity deforms linear elastically up to the onset of yielding. A Hertzian pressure distribution in contact with a coating, with and without friction, was modeled to determine the maximum contact pressure that can induce yielding in the coating. It was then assumed that the pad asperity deforms fully-plastically. A uniform pressure distribution in contact with a coating, with and without friction, was modeled to determine the maximum contact pressure required to induce yielding in the coating. The maximum pressure was then related to the pad asperity hardness for both contact pressure distributions. Finally, statistical asperity contact models were developed to relate the pad asperity radius of curvature to the type of asperity deformation, i.e. elastic at the onset of yielding or fully-plastic. As a result of these models, expressions that relate Cu coating scratching to the ratio of pad-to-coating hardness, coefficient of friction, and pad asperity radius of curvature were developed. The scratching by pad asperity models were validated by performing single and multi-asperity sliding experiments. The effects of pad hardness, pad asperity radius of curvature, and coefficient of friction were related to the frequency and severity of scratching.&lt;/Abstract>
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