2026-09-21T01:04:24Zhttps://dspace.mit.edu/server/oai/requestoai:dspace.mit.edu:1721.1/685482022-01-13T07:54:21Zcom_1721.1_7582com_1721.1_7581col_1721.1_131023
Gregory C. Fu.
Arizpe, Luis (Luis Alfredo)
Massachusetts Institute of Technology. Dept. of Chemistry.
Massachusetts Institute of Technology. Department of Chemistry
2012-01-12T19:36:28Z
2012-01-12T19:36:28Z
2011
2011
http://hdl.handle.net/1721.1/68548
771931439
Thesis (S.M.)--Massachusetts Institute of Technology, Dept. of Chemistry, 2011.
Cataloged from PDF version of thesis.
Includes bibliographical references (p. 30-32).
The synthesis, structure, and reactivity properties of three iridium square planar complexes bearing the anionic phosphine ligand diphenylphosphidoboratabenzene (DPB) are described. Reactivity studies show a rate enhancement for the oxidative addition of a substituted benzyl bromide and Me₃SnBr with DPB as a ligand in place of triphenylphosphine. Two products from the oxidative addition of p-chlorobenzyl bromide have been isolated and structurally characterized.
by Luis Arizpe.
S.M.
60 p.
eng
Massachusetts Institute of Technology
M.I.T. theses are protected by
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http://dspace.mit.edu/handle/1721.1/7582
Chemistry.
Synthesis, characterization, and reactivity studies of iridium complexes bearing the ligand diphenylphosphidoboratabenzene
Thesis
application/pdf
Publication
unknown
unknown
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