2026-09-19T04:05:39Zhttps://dspace.mit.edu/server/oai/requestoai:dspace.mit.edu:1721.1/795492022-01-13T07:55:22Zcom_1721.1_7582com_1721.1_7581col_1721.1_131022
W. Craig Carter, Yet-Ming Chiang, and Christopher A. Schuh.
Brunini, Victor Eric
Massachusetts Institute of Technology. Department of Materials Science and Engineering.
Massachusetts Institute of Technology. Department of Materials Science and Engineering
2013-07-10T14:53:48Z
2013-07-10T14:53:48Z
2012
2012
http://hdl.handle.net/1721.1/79549
851391484
Thesis (Ph. D.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, 2012.
Cataloged from PDF version of thesis.
Includes bibliographical references (p. 111-116).
A three-dimensional dynamic model of the recently introduced semi-solid flow battery system is developed and applied to address issues with important design and operation implications. Because of the high viscosity of semi-solid flow battery suspensions, alternative modes of operation not typically used in conventional redox flow battery systems must be explored to reduce pumping energy losses. Modeling results are presented and compared to experimental observations to address important considerations for both stoichiometric and intermittent flow operation. The importance of active material selection, and its impact on efficient stoichiometric flow operation is discussed. Electrochemically active zone considerations relevant to intermittent flow operation of semi-solid flow batteries (or other potential electronically conductive flow battery systems) are addressed. Finally, the use of the model as a design tool for optimizing flow channel design to improve system level performance is demonstrated.
by Victor Eric Brunini.
Ph.D.
116 p.
eng
Massachusetts Institute of Technology
M.I.T. theses are protected by
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http://dspace.mit.edu/handle/1721.1/7582
Materials Science and Engineering.
Modeling and design of semi-solid flow batteries
Thesis
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Publication
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