<?xml version="1.0" encoding="UTF-8"?><?xml-stylesheet type="text/xsl" href="static/style.xsl"?><OAI-PMH xmlns="http://www.openarchives.org/OAI/2.0/" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:schemaLocation="http://www.openarchives.org/OAI/2.0/ http://www.openarchives.org/OAI/2.0/OAI-PMH.xsd"><responseDate>2026-09-19T22:45:37Z</responseDate><request verb="GetRecord" identifier="oai:dspace.mit.edu:1721.1/84387" metadataPrefix="dim">https://dspace.mit.edu/server/oai/request</request><GetRecord><record><header><identifier>oai:dspace.mit.edu:1721.1/84387</identifier><datestamp>2022-01-13T07:54:01Z</datestamp><setSpec>com_1721.1_7582</setSpec><setSpec>com_1721.1_7581</setSpec><setSpec>col_1721.1_131023</setSpec></header><metadata><dim:dim xmlns:dim="http://www.dspace.org/xmlns/dspace/dim" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns:doc="http://www.lyncode.com/xoai" xsi:schemaLocation="http://www.dspace.org/xmlns/dspace/dim http://www.dspace.org/schema/dim.xsd">
   <dim:field mdschema="dc" element="contributor" qualifier="advisor" lang="en_US">Vladimir Bulović and Jeffrey H. Lang.</dim:field>
   <dim:field mdschema="dc" element="contributor" qualifier="author" lang="en_US">Niroui, Farnaz</dim:field>
   <dim:field mdschema="dc" element="contributor" qualifier="other" lang="en_US">Massachusetts Institute of Technology. Department of Electrical Engineering and Computer Science.</dim:field>
   <dim:field mdschema="dc" element="contributor" qualifier="department">Massachusetts Institute of Technology. Department of Electrical Engineering and Computer Science</dim:field>
   <dim:field mdschema="dc" element="date" qualifier="accessioned">2014-01-23T18:40:42Z</dim:field>
   <dim:field mdschema="dc" element="date" qualifier="available">2014-01-23T18:40:42Z</dim:field>
   <dim:field mdschema="dc" element="date" qualifier="issued" lang="en_US">2013</dim:field>
   <dim:field mdschema="dc" element="identifier" qualifier="uri">http://hdl.handle.net/1721.1/84387</dim:field>
   <dim:field mdschema="dc" element="identifier" qualifier="oclc" lang="en_US">867641225</dim:field>
   <dim:field mdschema="dc" element="description" lang="en_US">Thesis (S.M.)--Massachusetts Institute of Technology, Dept. of Electrical Engineering and Computer Science, 2013.</dim:field>
   <dim:field mdschema="dc" element="description" lang="en_US">Cataloged from PDF version of thesis.</dim:field>
   <dim:field mdschema="dc" element="description" lang="en_US">Includes bibliographical references (pages 101-105).</dim:field>
   <dim:field mdschema="dc" element="description" qualifier="abstract" lang="en_US">Nanoelectromechanical (NEM) switches exhibit abrupt switching behavior and near-zero leakage current making them promising alternatives to conventional semiconductor switches. However, they require high actuation voltages and commonly suffer from permanent adhesion of device components leading to failure. This thesis proposes a novel NEM switch, or "squitch", that overcomes these challenges by electromechanical modulation of tunneling current through a nanometer-thick gap defined by an organic thin-film sandwiched between two electrodes. The switching is initiated by an applied voltage compressing the organic film to reduce the tunneling width leading to an exponential increase in the tunneling current. The deformed organic material prevents direct contact of the electrodes, while also providing the restoring force necessary to turn off the switch when the electrostatic force is removed, mitigating stiction-induced failure. In this thesis, the feasibility of the proposed switching mechanism is investigated through theoretical analysis of two- and three-terminal devices, demonstrating the possibility of energy efficient operation in the sub-1 V regime, with nanoseconds switching time and a large on-off current ratio of greater than 106. Based on the theoretical studies, design requirements are identified to guide the fabrication process of the proposed devices. Various methods of fabricating these devices have been developed, the details of which are outlined in this work.</dim:field>
   <dim:field mdschema="dc" element="description" qualifier="statementofresponsibility" lang="en_US">by Farnaz Niroui.</dim:field>
   <dim:field mdschema="dc" element="description" qualifier="degree" lang="en_US">S.M.</dim:field>
   <dim:field mdschema="dc" element="format" qualifier="extent" lang="en_US">105 pages</dim:field>
   <dim:field mdschema="dc" element="language" qualifier="iso" lang="en_US">eng</dim:field>
   <dim:field mdschema="dc" element="publisher" lang="en_US">Massachusetts Institute of Technology</dim:field>
   <dim:field mdschema="dc" element="rights" lang="en_US">M.I.T. theses are protected by 
copyright. They may be viewed from this source for any purpose, but 
reproduction or distribution in any format is prohibited without written 
permission. See provided URL for inquiries about permission.</dim:field>
   <dim:field mdschema="dc" element="rights" qualifier="uri" lang="en_US">http://dspace.mit.edu/handle/1721.1/7582</dim:field>
   <dim:field mdschema="dc" element="subject" lang="en_US">Electrical Engineering and Computer Science.</dim:field>
   <dim:field mdschema="dc" element="title" lang="en_US">Electromechanical modulation of electrical conduction through organic thin films for switching applications</dim:field>
   <dim:field mdschema="dc" element="type" lang="en_US">Thesis</dim:field>
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   <dim:field mdschema="others" element="access-status">unknown</dim:field>
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   	&lt;Title>Electromechanical modulation of electrical conduction through organic thin films for switching applications&lt;/Title>
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   	&lt;PublicationDate>2013&lt;/PublicationDate>
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        	&lt;DisplayName>Niroui, Farnaz&lt;/DisplayName>
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            &lt;DisplayName>Massachusetts Institute of Technology&lt;/DisplayName>
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    &lt;License>http://dspace.mit.edu/handle/1721.1/7582&lt;/License>
    &lt;Keyword>Electrical Engineering and Computer Science.&lt;/Keyword>
   	&lt;Abstract>Nanoelectromechanical (NEM) switches exhibit abrupt switching behavior and near-zero leakage current making them promising alternatives to conventional semiconductor switches. However, they require high actuation voltages and commonly suffer from permanent adhesion of device components leading to failure. This thesis proposes a novel NEM switch, or &amp;quot;squitch&amp;quot;, that overcomes these challenges by electromechanical modulation of tunneling current through a nanometer-thick gap defined by an organic thin-film sandwiched between two electrodes. The switching is initiated by an applied voltage compressing the organic film to reduce the tunneling width leading to an exponential increase in the tunneling current. The deformed organic material prevents direct contact of the electrodes, while also providing the restoring force necessary to turn off the switch when the electrostatic force is removed, mitigating stiction-induced failure. In this thesis, the feasibility of the proposed switching mechanism is investigated through theoretical analysis of two- and three-terminal devices, demonstrating the possibility of energy efficient operation in the sub-1 V regime, with nanoseconds switching time and a large on-off current ratio of greater than 106. Based on the theoretical studies, design requirements are identified to guide the fabrication process of the proposed devices. Various methods of fabricating these devices have been developed, the details of which are outlined in this work.&lt;/Abstract>
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