<?xml version="1.0" encoding="UTF-8"?><?xml-stylesheet type="text/xsl" href="static/style.xsl"?><OAI-PMH xmlns="http://www.openarchives.org/OAI/2.0/" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:schemaLocation="http://www.openarchives.org/OAI/2.0/ http://www.openarchives.org/OAI/2.0/OAI-PMH.xsd"><responseDate>2026-09-20T09:03:10Z</responseDate><request verb="GetRecord" identifier="oai:dspace.mit.edu:1721.1/98548" metadataPrefix="dim">https://dspace.mit.edu/server/oai/request</request><GetRecord><record><header><identifier>oai:dspace.mit.edu:1721.1/98548</identifier><datestamp>2022-01-13T07:55:14Z</datestamp><setSpec>com_1721.1_7582</setSpec><setSpec>com_1721.1_7581</setSpec><setSpec>com_1721.1_91570</setSpec><setSpec>col_1721.1_131023</setSpec><setSpec>col_1721.1_91571</setSpec></header><metadata><dim:dim xmlns:dim="http://www.dspace.org/xmlns/dspace/dim" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns:doc="http://www.lyncode.com/xoai" xsi:schemaLocation="http://www.dspace.org/xmlns/dspace/dim http://www.dspace.org/schema/dim.xsd">
   <dim:field mdschema="dc" element="contributor" qualifier="advisor" lang="en_US">Daniel R. Cohn.</dim:field>
   <dim:field mdschema="dc" element="contributor" qualifier="author" lang="en_US">Acocella, Angela J. (Angela Josephine)</dim:field>
   <dim:field mdschema="dc" element="contributor" qualifier="other" lang="en_US">Massachusetts Institute of Technology. Technology and Policy Program.</dim:field>
   <dim:field mdschema="dc" element="contributor" qualifier="department">Massachusetts Institute of Technology. Engineering Systems Division</dim:field>
   <dim:field mdschema="dc" element="date" qualifier="accessioned">2015-09-17T17:41:50Z</dim:field>
   <dim:field mdschema="dc" element="date" qualifier="available">2015-09-17T17:41:50Z</dim:field>
   <dim:field mdschema="dc" element="date" qualifier="copyright" lang="en_US">2015</dim:field>
   <dim:field mdschema="dc" element="date" qualifier="issued" lang="en_US">2015</dim:field>
   <dim:field mdschema="dc" element="identifier" qualifier="uri">http://hdl.handle.net/1721.1/98548</dim:field>
   <dim:field mdschema="dc" element="identifier" qualifier="oclc" lang="en_US">920673913</dim:field>
   <dim:field mdschema="dc" element="description" lang="en_US">Thesis: S.M. in Technology and Policy, Massachusetts Institute of Technology, Engineering Systems Division, 2015.</dim:field>
   <dim:field mdschema="dc" element="description" lang="en_US">This electronic version was submitted by the student author.  The certified thesis is available in the Institute Archives and Special Collections.</dim:field>
   <dim:field mdschema="dc" element="description" lang="en_US">Cataloged from student-submitted PDF version of thesis.</dim:field>
   <dim:field mdschema="dc" element="description" lang="en_US">Includes bibliographical references (pages 88-93).</dim:field>
   <dim:field mdschema="dc" element="description" qualifier="abstract" lang="en_US">As global energy demands grow and environmental concerns over resource extraction methods intensify, high impact solutions are becoming increasingly essential. Venting and flaring of associated natural gas represents significant environmental and financial losses yet it continues in the North Dakota Bakken oil play. The valuable gas resource is wasted due to unfavorable economics and limited pipeline capacity. Similarly in India, underdeveloped gas transport infrastructure and restrictive regulatory frameworks prevent distribution and marketing of natural gas from the northeast regions, leaving it stranded in marginal fields. This thesis establishes a techno-economic model, utilizing Aspen Plus chemical processing software, and a discounted cash flow model to estimate economic feasibility of implementing MIT engine reformer-based gas-to-liquids (GTL) systems in the US or India. The system reforms natural gas via partial oxidation into synthesis gas (syngas) in the cylinders of an internal combustion engine, and can significantly reduce capital costs over conventional GTL reforming processes. The engine is operated in fuel rich conditions to generate the syngas, which is synthesized into methanol and dimethyl ether (DME). Once produced on-site, these liquids are more easily transported than gases. This study assesses the regulatory structures surrounding the upstream methane resource and downstream end product marketability for three scenarios: use of DME to replace existing local (1) diesel and (2) liquefied petroleum gas (LPG), or (3) sale of methanol as a commodity chemical on domestic or global markets. The analysis shows the system is economical in both locations. In the US, the minimum economically efficient production capacity with a 1-2 year payback period is 400,000- 860,000 standard cubic feet per day (scfpd) of natural gas for the range of end use scenarios considered. Differences in costs and product market characteristics in India result in a minimum efficient capacity of 330,000-810,000 scfpd of natural gas for the three scenarios.</dim:field>
   <dim:field mdschema="dc" element="description" qualifier="statementofresponsibility" lang="en_US">by Angela J. Acocella.</dim:field>
   <dim:field mdschema="dc" element="description" qualifier="degree" lang="en_US">S.M. in Technology and Policy</dim:field>
   <dim:field mdschema="dc" element="format" qualifier="extent" lang="en_US">107 pages</dim:field>
   <dim:field mdschema="dc" element="language" qualifier="iso" lang="en_US">eng</dim:field>
   <dim:field mdschema="dc" element="publisher" lang="en_US">Massachusetts Institute of Technology</dim:field>
   <dim:field mdschema="dc" element="rights" lang="en_US">M.I.T. theses are protected by copyright. They may be viewed from this source for any purpose, but reproduction or distribution in any format is prohibited without written permission. See provided URL for inquiries about permission.</dim:field>
   <dim:field mdschema="dc" element="rights" qualifier="uri" lang="en_US">http://dspace.mit.edu/handle/1721.1/7582</dim:field>
   <dim:field mdschema="dc" element="subject" lang="en_US">Engineering Systems Division.</dim:field>
   <dim:field mdschema="dc" element="subject" lang="en_US">Technology and Policy Program.</dim:field>
   <dim:field mdschema="dc" element="title" lang="en_US">System model of small-scale gas-to-methanol conversion by engine reformers</dim:field>
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   	&lt;Title>System model of small-scale gas-to-methanol conversion by engine reformers&lt;/Title>
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   	&lt;PublicationDate>2015&lt;/PublicationDate>
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        	&lt;DisplayName>Acocella, Angela J. (Angela Josephine)&lt;/DisplayName>
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   	&lt;Abstract>As global energy demands grow and environmental concerns over resource extraction methods intensify, high impact solutions are becoming increasingly essential. Venting and flaring of associated natural gas represents significant environmental and financial losses yet it continues in the North Dakota Bakken oil play. The valuable gas resource is wasted due to unfavorable economics and limited pipeline capacity. Similarly in India, underdeveloped gas transport infrastructure and restrictive regulatory frameworks prevent distribution and marketing of natural gas from the northeast regions, leaving it stranded in marginal fields. This thesis establishes a techno-economic model, utilizing Aspen Plus chemical processing software, and a discounted cash flow model to estimate economic feasibility of implementing MIT engine reformer-based gas-to-liquids (GTL) systems in the US or India. The system reforms natural gas via partial oxidation into synthesis gas (syngas) in the cylinders of an internal combustion engine, and can significantly reduce capital costs over conventional GTL reforming processes. The engine is operated in fuel rich conditions to generate the syngas, which is synthesized into methanol and dimethyl ether (DME). Once produced on-site, these liquids are more easily transported than gases. This study assesses the regulatory structures surrounding the upstream methane resource and downstream end product marketability for three scenarios: use of DME to replace existing local (1) diesel and (2) liquefied petroleum gas (LPG), or (3) sale of methanol as a commodity chemical on domestic or global markets. The analysis shows the system is economical in both locations. In the US, the minimum economically efficient production capacity with a 1-2 year payback period is 400,000- 860,000 standard cubic feet per day (scfpd) of natural gas for the range of end use scenarios considered. Differences in costs and product market characteristics in India result in a minimum efficient capacity of 330,000-810,000 scfpd of natural gas for the three scenarios.&lt;/Abstract>
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