Effective thermal conductivity measurements relevant to deep borehole nuclear waste disposal

Abstract

The objective of this work was to measure the effective thermal conductivity of a number of materials (particle beds, and fluids) proposed for use in and around canisters for disposal of high level nuclear waste in deep boreholes. This information is required to insure that waste temperatures will not exceed tolerable limits. Such experimental verification is essential because analytical models and empirical correlations can not accurately predict effective thermal conductivities for complex configurations of poorly characterized media, such as beds of irregular particles of mixed sizes. The experimental apparatus consisted of a 2.54 cm. diameter cylindrical heater (heated length = 0.5 m) , surrounded by a 5.0 cm inner diameter steel tube. Six pairs of thermocouples were located axially on the inside of the heater sheath, and in grooves on the air-fan-cooled outer tube. Test media were used to fill the annular gap, and the temperature drop across the gap measured at several power levels covering the range of heat fluxes expected on a waste canister soon after emplacement. Values of effective thermal conductivity were measured for air, water; particle beds of sand, SiC, graphite and aluminum; and an air gap subdivided by a thin metal sleeve insert. Results are compared to literature values and analytical models for conduction, convection and radiation. Agreement within a factor of 2 was common, and the results confirm the adequacy, and reduce the uncertainty of prior borehole system design calculations. All particle bed data fell between 0.3 and 0.5 W/moC, hence other attributes can determine usage.