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1 |
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Lecture 1: Vision Statement, Administrative Details. Introduction. Taxonomy of Chemical Species. Origins of Modern Chemistry. |
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Ch. 1 |
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2 |
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Lecture 2: Classification Schemes for the Elements. Mendeleyev and the Periodic Table. Atomic Structure. |
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Ch. 1, Ch. 2, Appendix A, Elemental Bibliography |
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3 |
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Lecture 3: Rutherford Model of the Atom, Bohr Model of Hydrogen. |
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Ch. 3.1, 3.5-3.8 (text) |
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Quiz 1A with Solutions (PDF)
Quiz 1B with Solutions (PDF) |
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LN 1, pp. 2-5 (PDF) |
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Homework #1 Solutions (PDF)
Homework #1 Solutions, 2nd Installment (PDF) |
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4 |
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Lecture 4: Atomic Spectra of Hydrogen, Matter/Energy Interactions Involving Atomic Hydrogen. |
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Ch. 3.3, 3.4, 3.9, 3.10 (text) |
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LN 1, pp. 5-16 (PDF) |
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5 |
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Lecture 5: The Shell Model (Bohr-Sommerfeld Model) and Multi-electron Atoms. Quantum Numbers: n, l, m, s. |
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Ch. 3.2, 3.10-3.12, 3.15-3.18 (text) |
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LN 1 (PDF) |
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6 |
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Lecture 6: De Broglie, Heisenberg, and Schrödinger. The Aufbau Principle, Pauli Exclusion Principle, and Hund's Rules. Photoelectron Spectroscopy. Average Valence Electron Energy. |
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Ch. 3.24, 3.25, 5.1-5.7, 5.10 (text) |
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Quiz 2A with Solutions (PDF)
Quiz 2B with Solutions (PDF) |
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LN 2 (PDF) |
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Homework #2 (PDF)
Homework #2 Solutions (PDF) |
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7 |
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Lecture 7: Octet Stability by Electron Transfer: Ionic Bonding. Properties of Ionic Compounds: Crystal Lattice Energy. |
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Ch. 5.1-5.7, 5.10 (text) |
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LN 2, pp. 1-12 (PDF) |
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8 |
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Lecture 8: Born-Haber Cycle. Octet Stability by Electron Sharing: Covalent Bonding. Lewis Structures. Hybridization. |
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Ch. 4.1-4.7, 4.10-4.12, 4.17 (text) |
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9 |
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Lecture 9: Electronegativity, Partial Charge, Polar Bonds and Polar Molecules. Ionic Character of CovalentBbonds, Pauling's Calculation of Heteronuclear Bond Energies. |
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Ch. 5.7, 5.10, 4A.1, 4A.3 (text) |
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Quiz 3A with Solutions (PDF)
Quiz 3B with Solutions (PDF) |
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Homework #3 (PDF) |
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10 |
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Lecture 10: LCAO MO, Energy Level Diagrams for H2, He2, Li2. Hybridization, Double Bonds and Triple Bonds, Paramagnetism and Diamagetism. |
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Ch. 4A.1-4A.4, 14-4-14.6, 8.2, 8.9 (text) |
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Test 1 (PDF) |
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LN 2, pp.12- end (PDF) |
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11 |
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Lecture 11: The Shapes of Molecules, Electron Domain Theory, Secondary Bonding. |
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Ch. 4.14, 4.15 (text) |
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LN 2, pp. 25-26(PDF), LN 3 (PDF) |
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12 |
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Lecture 12: Metallic Bonding, Band Theory of Solids (Heitler and London), Band Gaps in Metals, Semiconductors, and Insulators, Absorption Edge of a Semiconductor. |
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Ch. 5.9-5.11, 9.4 (text); M.12 (modules) |
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Quiz 4A with Solutions (PDF)
Quiz 4B with Solutions (PDF) |
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LN 3 (PDF) |
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Homework #4 (PDF)
Homework #4 Solutions (PDF) |
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13 |
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Lecture 13: Intrinsic and Extrinsic Semiconductors, Doping, Compound Semiconductors, Molten Semiconductors. |
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M.12 (modules) |
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LN 4 (PDF) |
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14 |
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Lecture 14: Introduction to the Solid State, the 7 Crystal Systems, the 14 Bravais Lattices. |
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9.6-9.12 (text), M.1-M.4, M.8 (modules); pp. 3-11 (supplement) |
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LN 4 (PDF) |
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15 |
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Lecture 15: Properties of Cubic Crystals: Simple Cubic, Face-centered Cubic, Body-centered Cubic, Diamond Cubic. Crystal Coordinate Systems, Miller Indices. |
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9.6-9.12 (text); M.1-M.6 (modules); pp. 3-23; 150-155; 167-174 (supplement) |
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Quiz 5A with Solutions (PDF)
Quiz 5B with Solutions (PDF) |
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LN 5, pp. 1-9 (PDF) |
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Homework #5 and Solutions (PDF) |
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16 |
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Lecture 16: Characterization of Atomic Structure: The Generation of X-rays and Moseley's Law. |
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pp. 139-141; 144-149; 175-181(supplement) |
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LN 5 (PDF) |
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17 |
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Lecture 17: X-ray Spectra, Bragg's Law. |
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pp. 26-31; 186-191 (supplement) |
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LN 5 (PDF) |
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18 |
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Lecture 18: X-ray Diffraction of Crystals: Diffractometry, Debye-Scherrer, Laue. Crystal Symmetry. |
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pp. 26-31 (supplement) |
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Quiz 6A with Solutions (PDF)
Quiz 6B with Solutions (PDF) |
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LN 6 (PDF) |
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Homework #6 (PDF)
Homework #6 Solutions (PDF) |
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19 |
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Lecture 19: Defects in Crystals: Point Defects, Line Defects, Interfacial Defects, Voids. |
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M.11 (modules); pp. 39-43, 47-53 (supplement) |
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LN 7, pp. 1-3, 5-9 (PDF) |
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20 |
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Lecture 20: Amorphous Solids, Glass Formation, Inorganic Glasses: Silicates. |
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9.1, 9.2 (text); M.15 (modules); pp. 31-32 (supplement) |
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LN 7, pp. 1-3, 5-9 (PDF) |
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21 |
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Lecture 21: Engineered Glasses: Network Formers, Network Modifiers, Intermediates. Properties of Silicate Glasses. Metallic Glass. |
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9.1, 9.2 (text); M.15 (modules); pp. 31-32 (supplement) |
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Test 2 (PDF) |
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LN 8 (PDF) |
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Homework #7 (PDF)
Homework #7 Solutions (PDF) |
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22 |
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Lecture 22: Chemical Kinetics: the Rate Equation, Order of Reaction, Rate Laws for Zeroth, First, and Second Order Reactions. Temperature Dependence of Rate of Reaction. |
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10.1-10.4, 14.1-14.8, 14.10, 14.11 (text) |
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LN 9, pp. 1-6 (PDF) |
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23 |
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Lecture 23: Diffusion: Fick's First Law and Steady-state Diffusion, Dependence of the Diffusion Coefficient on Temperature and on Atomic Arrangement. |
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pp. 63-68; 85-95 (supplement) |
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LN 9, all (PDF) |
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24 |
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Lecture 24: Fick's Second Law (FSL) and Transient-state Diffusion; Error Function Solutions to FSL. |
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pp. 68-78, 95-101 (supplement) |
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Quiz 8A with Solutions (PDF)
Quiz 8B with Solutions (PDF) |
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Homework #8 (PDF)
Homework #8 Solutions (PDF) |
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25 |
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Lecture 25: Solutions: Solute, Solvent, Solution, Solubility Rules, Solubility Product. |
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8.10-8.13, 8.15 (text); SOL.1-SOL.10(modules) |
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26 |
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Lecture 26: Acids and Bases: Arrhenius, Brønsted-Lowry, and Lewis Definitions, Acid Strength and pH. |
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Ch. 11 (text) |
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27 |
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Lecture 27: Organic Chemistry: Basic Concepts, Alkanes, Alkenes, Alkynes, Aromatics, Functional Groups, Alcohols and Ethers, Aldehydes and Ketones, Esters, Amines. |
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01.1-01.7, 01.10-01.11, 01.13, 01.14, 02.1, 02.3, 02.4 (modules) |
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Quiz 9A with Solutions (PDF)
Quiz 9B with Solutions (PDF) |
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Homework #9 (PDF)
Homework #9 Solutions (PDF) |
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28 |
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Lecture 28: Organic Glasses--Polymers: Synthesis by Addition Polymerization and by Condensation Polymerization. |
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P.1-P.3, P.7-P.9 (modules) |
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29 |
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Lecture 29: Structure-property Relationships in Polymers, Crystalline Polymers. |
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P.1-P.3, P.7-P.9 (modules) |
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30 |
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Lecture 30: Biochemistry: the Amino Acids, Peptides, and Proteins. |
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BIO.1 - BIO.3; BIO.5 |
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Test 3 (PDF) |
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Homework #10 (PDF)
Homework #10 Solutions (PDF) |
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31 |
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Lecture 31: Protein Structure: Primary, Secondary, Tertiary; Denaturing of Proteins. |
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BIO.6, BIO.9 |
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32 |
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Lecture 32: Lipids: Self Assembly into Bilayers. Nucleic Acids, DNA, Encoding Information for Protein Synthesis. Electrochemistry of Batteries and Fuel Cells. |
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BIO.6, BIO.9 |
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33 |
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Lecture 33: Phase Diagrams--Basic Definitions: Phase, Component, Equilibrium; One-component Phase Diagrams. |
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pp. 103-107 (16.1) (supplement) |
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Quiz 11A with Solutions (PDF)
Quiz 11B with Solutions (PDF) |
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LN 10 Part A 1-3 (PDF) |
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Homework #11 with Solutions (PDF - 1.9 MB) |
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34 |
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Lecture 34: Two-Ccomponent Phase Diagrams: Complete Solid solubility. Lever Rule. |
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pp. 107-113 (16.2-16.3) (supplement) |
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LN 10 Part B 1-9 (PDF) |
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35 |
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Lecture 35: Two-Component Phase Diagrams: Limited Solid Solubility. Lever Rule. |
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pp. 113-119 (16.4) (supplement) |
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LN 10 Part B 1-9 (PDF) |
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36 |
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Lecture 36: Wrap-up: Closing Remarks About 3.091. Student Course Evaluations. |
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Quiz 12A with Solutions (PDF)
Quiz 12B with Solutions (PDF)
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Homework #12 with Solutions (PDF) |
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