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Unexpected Formation of Hexasubstituted Arenes through a 2-fold Palladium-Mediated Ligand Arylation

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sword-2020-10-19T14:33:09.original.xml (130 B)
Original SWORD entry document
Author(s)
Wagen, Corin C
•
Ingoglia, Bryan T
•
Buchwald, Stephen L
Journal
Journal of Organic Chemistry
Publisher
American Chemical Society (ACS)
Version
Author's final manuscript
Abstract
© 2019 American Chemical Society. A rearrangement reaction of biarylphosphine-supported Pd(II) complexes was employed to synthesize 1,3,5-triaryl 2,4,6-triisopropylbenzene compounds, a class of molecules that has not previously been reported. The strain of the central hexasubstituted ring was investigated via X-ray crystallography.
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DOI of Published Version
10.1021/ACS.JOC.9B02091
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