Advances in understanding comproportionation and disproportionation in nickel catalysis
Name
10.1515_pac-2024-0106.pdf
Size
884.89 KB
Format
Adobe PDF
Checksum (MD5)
91799695d6d4ed7c24e5d509fc04b17e
Author(s)
Day, Craig
Date Issued
March 21, 2024
Journal
Pure and Applied Chemistry
Publisher
Walter de Gruyter GmbH
Citation
Day, Craig S.. "Advances in understanding comproportionation and disproportionation in nickel catalysis" Pure and Applied Chemistry, vol. 96, no. 3, 2024, pp. 437-446.
Version
Final published version
Abstract
Disproportionation and comproportionation reactions have become routinely proposed events in modern synthetic endevours that use nickel catalysts. This new found appreciation from practitioners in the field for these electron transfer reactions has largely stemmed from our improved understanding of catalytic reactions. These studies have shown evidence of the ability of nickel complexes to occupy odd and even oxidation states which are critical to dictating reactivity. Comproportionation and disproportionation reactions shuttle nickel complexes between these oxidation states and are essential to the formation of either on-cycle or off-cycle species. This review will cover these fundamental reactions, and provide information about their role in catalysis.
Subjects
Catalysis
nickel
sustainable chemistry
electron transfer
comproportionation
disproportionation
2023 IUPAC-Solvay Award
MIT Department
Massachusetts Institute of Technology. Department of Chemistry
Terms of Use
Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use.
Persistent DSpace Link
DOI of Published Version
https://doi.org/10.1515/pac-2024-0106
