dc.contributor.author | Hakalla, R. | |
dc.contributor.author | Niu, M. L. | |
dc.contributor.author | Salumbides, E. J. | |
dc.contributor.author | Heays, A. N. | |
dc.contributor.author | Stark, G. | |
dc.contributor.author | Lyons, J. R. | |
dc.contributor.author | Eidelsberg, M. | |
dc.contributor.author | Lemaire, J. L. | |
dc.contributor.author | Federman, S. R. | |
dc.contributor.author | Zachwieja, M. | |
dc.contributor.author | Szajna, W. | |
dc.contributor.author | Kolek, P. | |
dc.contributor.author | Piotrowska, I. | |
dc.contributor.author | Ostrowska-Kopeć, M. | |
dc.contributor.author | Kępa, R. | |
dc.contributor.author | de Oliveira, N. | |
dc.contributor.author | Ubachs, W. | |
dc.contributor.author | Field, Robert W | |
dc.date.accessioned | 2017-07-05T15:56:57Z | |
dc.date.available | 2017-07-05T15:56:57Z | |
dc.date.issued | 2016-03 | |
dc.date.submitted | 2016-01 | |
dc.identifier.issn | 2046-2069 | |
dc.identifier.uri | http://hdl.handle.net/1721.1/110462 | |
dc.description.abstract | High-accuracy dispersive optical spectroscopy measurements in the visible (VIS) region have been performed on the less-abundant [superscript 12]C[superscript 17]O isotopologue, observing high-resolution emission bands of the B[superscript 1]Σ+ (υ = 0) → A[superscript 1]Π (υ = 3, 4, and 5) Ångström system. These are combined with high-resolution photoabsorption measurements of the [superscript 12]C[superscript 17]O B[superscript 1]Σ[superscript +] (υ = 0) ← X[superscript 1]Σ+ (υ = 0) and C[superscript 1]Σ+ (υ = 0) ← X[superscript 1]Σ+ (υ = 0) Hopfield–Birge bands recorded with the vacuum-ultraviolet (VUV) Fourier transform spectrometer, installed on the DESIRS beamline at the SOLEIL synchrotron. The frequencies of 429 observed transitions have been determined in the 15 100–18 400 cm[superscript −1] and 86 900–92 100 cm[superscript −1] regions with an absolute accuracy of up to 0.003 cm[superscript −1] and 0.005 cm[superscript −1] for the B–A, and B–X, C–X systems, respectively. These new experimental data were combined with data from the previously analysed C → A and B → A systems. The comprehensive data set, 982 spectral lines belonging to 12 bands, was included in a deperturbation analysis of the A[superscript 1]Π, υ = 1–5 levels of [superscript 12]C[superscript 17]O, taking into account interactions with levels in the d[superscript 3]Δ[subscript i], e[superscript 3]Σ[superscript −], a[superscript ′3]Σ[superscript +], I[superscript 1]Σ− and D[superscript 1]Δ states. The A[superscript 1]Π and perturber states were described in terms of a set of deperturbed molecular constants, spin–orbit and L-uncoupling interaction parameters, equilibrium constants, 309 term values, as well as isotopologue-independent spin–orbit and rotation-electronic perturbation parameters. | en_US |
dc.description.sponsorship | National Science Foundation (U.S.) (Grant CHE-1361865) | en_US |
dc.language.iso | en_US | |
dc.publisher | Royal Society of Chemistry | en_US |
dc.relation.isversionof | http://dx.doi.org/10.1039/c6ra01358a | en_US |
dc.rights | Creative Commons Attribution 3.0 Unported licence | en_US |
dc.rights.uri | http://creativecommons.org/licenses/by/3.0/ | en_US |
dc.source | Royal Society of Chemistry | en_US |
dc.title | VIS and VUV spectroscopy of of [superscript 12]C[superscript 17]O and deperturbation analysis of the A[superscript 1]Π, υ = 1–5 levels | en_US |
dc.type | Article | en_US |
dc.identifier.citation | Hakalla, R. et al. “VIS and VUV Spectroscopy of [superscript 12]C[superscript17]O and Deperturbation Analysis of the A[superscript 1] Π, υ = 1–5 Levels.” RSC Adv. 6.38 (2016): 31588–31606. © 2016 The Royal Society of Chemistry | en_US |
dc.contributor.department | Massachusetts Institute of Technology. Department of Chemistry | |
dc.contributor.mitauthor | Field, Robert W | |
dc.relation.journal | RSC Advances | en_US |
dc.eprint.version | Final published version | en_US |
dc.type.uri | http://purl.org/eprint/type/JournalArticle | en_US |
eprint.status | http://purl.org/eprint/status/PeerReviewed | en_US |
dspace.orderedauthors | Hakalla, R.; Niu, M. L.; Field, R. W.; Salumbides, E. J.; Heays, A. N.; Stark, G.; Lyons, J. R.; Eidelsberg, M.; Lemaire, J. L.; Federman, S. R.; Zachwieja, M.; Szajna, W.; Kolek, P.; Piotrowska, I.; Ostrowska-Kopeć, M.; Kępa, R.; de Oliveira, N.; Ubachs, W. | en_US |
dspace.embargo.terms | N | en_US |
dc.identifier.orcid | https://orcid.org/0000-0002-7609-4205 | |
mit.license | PUBLISHER_CC | en_US |
mit.metadata.status | Complete | |