dc.contributor.author | Hakalla, R. | |
dc.contributor.author | Niu, M.L. | |
dc.contributor.author | Heays, A.N. | |
dc.contributor.author | Salumbides, E.J. | |
dc.contributor.author | Stark, G. | |
dc.contributor.author | Lyons, J.R. | |
dc.contributor.author | Eidelsberg, M. | |
dc.contributor.author | Lemaire, J.L. | |
dc.contributor.author | Federman, S.R. | |
dc.contributor.author | de Oliveira, N. | |
dc.contributor.author | Ubachs, W. | |
dc.contributor.author | Field, Robert W | |
dc.date.accessioned | 2019-03-05T15:48:01Z | |
dc.date.available | 2019-03-05T15:48:01Z | |
dc.date.issued | 2017-03 | |
dc.identifier.issn | 0022-4073 | |
dc.identifier.uri | http://hdl.handle.net/1721.1/120726 | |
dc.description.abstract | The high-resolution B[superscript 1]Σ[superscript +]→A[superscript 1]Π (0, 0) and (0, 3) emission bands of the less-abundant [superscript 13]C[superscript 17]O isotopologue have been investigated by Fourier-transform spectroscopy in the visible region using a Bruker IFS 125HR spectrometer at an accuracy 0.003 cm[superscript -1]. These spectra are combined with high-resolution photoabsorption measurements of the [superscript 13]C[superscript 17]O B[superscript 1]Σ[superscript +]←X[superscript 1]Σ[superscript +] (0, 0), B[superscript 1]Σ[superscript +]←X[superscript 1]Σ[superscript +] (1, 0) and C[superscript 1]Σ[superscript +]←X[superscript 1]Σ[superscript +] (0, 0) bands recorded with an accuracy of 0.01 cm-1 using the vacuum ultraviolet Fourier-transform spectrometer, installed on the DESIRS beamline at the SOLEIL synchrotron. In the studied 17,950–22,500 cm[superscript -1] and 86,800–92,100 cm[superscript -1] regions, 480 transitions have been measured. These new experimental data were combined with data from the C→A and B→A systems, previously analyzed in [superscript 13]C[superscript 17]O. The frequencies of 1003 transitions derived from 12 bands were used to analyze the perturbations between the A[superscript 1]Π (υ=0–3) levels and rovibrational levels of the d[superscript 3]Δ[subscript i], e[superscript 3]Σ[superscript -], a[superscript '3]Σ[superscript +], I[superscript 1]Σ[superscript -] and D[superscript 1]Δ states as well as to a preliminary investigation of weak irregularities that appear in the B[superscript 1]Σ[superscript +] (υ=0) level. Deperturbed molecular constants and term values of the A[superscript 1]Π state were obtained. The spin-orbit and L-uncoupling interaction parameters as well as isotopologue-independent spin-orbit and rotation-electronic perturbation parameters were derived. | en_US |
dc.description.sponsorship | National Science Foundation (U.S.) (Grant CHE-1361865) | en_US |
dc.language.iso | en_US | |
dc.relation.isversionof | http://dx.doi.org/10.1016/j.jqsrt.2016.12.012 | en_US |
dc.rights | Creative Commons Attribution-NonCommercial-NoDerivs License | en_US |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | en_US |
dc.source | Prof. Field | en_US |
dc.title | Fourier-Transform Spectroscopy of [superscript 13]C[superscript 17]O and Deperturbation Analysis of the A[superscript 1]Π (υ=0–3) Levels | en_US |
dc.type | Article | en_US |
dc.identifier.citation | Hakalla, R., M.L. Niu, R.W. Field, A.N. Heays, E.J. Salumbides, G. Stark, J.R. Lyons, et al. “Fourier-Transform Spectroscopy of [superscript 13]C[superscript 17]O and Deperturbation Analysis of the A[superscript 1]Π (υ=0–3) Levels.” Journal of Quantitative Spectroscopy and Radiative Transfer 189 (March 2017): 312–328. | en_US |
dc.contributor.department | Massachusetts Institute of Technology. Department of Chemistry | en_US |
dc.contributor.approver | Field, Robert, W. | en_US |
dc.contributor.mitauthor | Field, Robert W | |
dc.relation.journal | Journal of Quantitative Spectroscopy and Radiative Transfer | en_US |
dc.eprint.version | Author's final manuscript | en_US |
dc.type.uri | http://purl.org/eprint/type/JournalArticle | en_US |
eprint.status | http://purl.org/eprint/status/PeerReviewed | en_US |
dspace.orderedauthors | Hakalla, R.; Niu, M.L.; Field, R.W.; Heays, A.N.; Salumbides, E.J.; Stark, G.; Lyons, J.R.; Eidelsberg, M.; Lemaire, J.L.; Federman, S.R.; de Oliveira, N.; Ubachs, W. | en_US |
dspace.embargo.terms | N | en_US |
dc.identifier.orcid | https://orcid.org/0000-0002-7609-4205 | |
mit.license | PUBLISHER_CC | en_US |