| dc.contributor.author | Narayan, Tarun Chandru | |
| dc.contributor.author | Miyakai, Tomoyo | |
| dc.contributor.author | Seki, Shu | |
| dc.contributor.author | Dinca, Mircea | |
| dc.date.accessioned | 2013-07-25T20:31:11Z | |
| dc.date.available | 2013-07-25T20:31:11Z | |
| dc.date.issued | 2012-08 | |
| dc.date.submitted | 2012-06 | |
| dc.identifier.issn | 0002-7863 | |
| dc.identifier.issn | 1520-5126 | |
| dc.identifier.uri | http://hdl.handle.net/1721.1/79703 | |
| dc.description.abstract | The tetratopic ligand tetrathiafulvalene-tetrabenzoate (H[subscript 4]TTFTB) is used to synthesize Zn[subscript 2](TTFTB), a new metal–organic framework that contains columnar stacks of tetrathiafulvalene and benzoate-lined infinite one-dimensional channels. The new MOF remains porous upon desolvation and exhibits charge mobility commensurate with some of the best organic semiconductors, confirmed by flash-photolysis-time-resolved microwave conductivity measurements. Zn[subscript 2](TTFTB) represents the first example of a permanently porous MOF with high charge mobility and may inspire further exploration of the electronic properties of these materials. | en_US |
| dc.description.sponsorship | United States. Dept. of Energy (Office of Basic Energy Sciences, Award Number DE-SC0006937) | en_US |
| dc.description.sponsorship | National Science Foundation (U.S.) (Massachusetts Institute of Technology, Dept. of Chemistry, Instrumentation Facility, CHE-9808061) | en_US |
| dc.description.sponsorship | National Science Foundation (U.S.) (Massachusetts Institute of Technology, Dept. of Chemistry, Instrumentation Facility, DBI-9729592) | en_US |
| dc.description.sponsorship | National Science Foundation (U.S.) (NSF MRSEC Program under award no. DMR-0819762) | en_US |
| dc.description.sponsorship | Japan Society for the Promotion of Science (NEXT Programs) | en_US |
| dc.language.iso | en_US | |
| dc.publisher | American Chemical Society | en_US |
| dc.relation.isversionof | http://dx.doi.org/10.1021/ja3059827 | en_US |
| dc.rights | Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use. | en_US |
| dc.source | Prof. Dinca via Erja Kajosalo | en_US |
| dc.title | High Charge Mobility in a Tetrathiafulvalene-Based Microporous Metal–Organic Framework | en_US |
| dc.type | Article | en_US |
| dc.identifier.citation | Narayan, Tarun C., Tomoyo Miyakai, Shu Seki, and Mircea Dincă 2012 High Charge Mobility in a Tetrathiafulvalene-Based Microporous Metal–Organic Framework. Journal of the American Chemical Society 134(31): 12932–12935. | en_US |
| dc.contributor.department | Massachusetts Institute of Technology. Department of Chemistry | en_US |
| dc.contributor.approver | Dinca, Mircea | en_US |
| dc.contributor.mitauthor | Narayan, Tarun Chandru | en_US |
| dc.contributor.mitauthor | Dinca, Mircea | en_US |
| dc.relation.journal | Journal of the American Chemical Society | en_US |
| dc.eprint.version | Author's final manuscript | en_US |
| dc.type.uri | http://purl.org/eprint/type/JournalArticle | en_US |
| eprint.status | http://purl.org/eprint/status/PeerReviewed | en_US |
| dspace.orderedauthors | Narayan, Tarun C.; Miyakai, Tomoyo; Seki, Shu; Dincă, Mircea | en_US |
| dc.identifier.orcid | https://orcid.org/0000-0002-1262-1264 | |
| mit.license | PUBLISHER_POLICY | en_US |
| mit.metadata.status | Complete | |
