| dc.contributor.author | Morten, Christopher J. | |
| dc.contributor.author | Jamison, Timothy F. | |
| dc.date.accessioned | 2015-10-29T17:45:38Z | |
| dc.date.available | 2015-10-29T17:45:38Z | |
| dc.date.issued | 2009-06 | |
| dc.date.submitted | 2009-05 | |
| dc.identifier.issn | 00404020 | |
| dc.identifier.uri | http://hdl.handle.net/1721.1/99512 | |
| dc.description.abstract | This report describes a number of new synthetic approaches toward methyl-substituted mono- and diepoxy alcohols that serve as substrates for endo-selective epoxide-opening cascades. The key transformations involve the manipulation of alkynes. Highlighted are the directed methylmetalation of bishomopropargylic alcohols, the bromoallylation of alkynes, and Pd-catalyzed cross-coupling between an alkenyl boronate ester and allylic bromides. | en_US |
| dc.description.sponsorship | National Institute of General Medical Sciences (U.S.) (GM72566) | en_US |
| dc.description.sponsorship | Massachusetts Institute of Technology. Department of Chemistry (George Buchi Summer Graduate Fellowship) | en_US |
| dc.language.iso | en_US | |
| dc.publisher | Elsevier | en_US |
| dc.relation.isversionof | http://dx.doi.org/10.1016/j.tet.2009.05.074 | en_US |
| dc.rights | Creative Commons Attribution-Noncommercial-NoDerivatives | en_US |
| dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | en_US |
| dc.source | PMC | en_US |
| dc.title | New synthetic strategies for the stereocontrolled synthesis of substituted ‘skipped’ diepoxides | en_US |
| dc.type | Article | en_US |
| dc.identifier.citation | Morten, Christopher J., and Timothy F. Jamison. “New Synthetic Strategies for the Stereocontrolled Synthesis of Substituted ‘skipped’ Diepoxides.” Tetrahedron 65, no. 33 (August 2009): 6648–6655. | en_US |
| dc.contributor.department | Massachusetts Institute of Technology. Department of Chemistry | en_US |
| dc.contributor.mitauthor | Morten, Christopher J. | en_US |
| dc.contributor.mitauthor | Jamison, Timothy F. | en_US |
| dc.relation.journal | Tetrahedron | en_US |
| dc.eprint.version | Author's final manuscript | en_US |
| dc.type.uri | http://purl.org/eprint/type/JournalArticle | en_US |
| eprint.status | http://purl.org/eprint/status/PeerReviewed | en_US |
| dspace.orderedauthors | Morten, Christopher J.; Jamison, Timothy F. | en_US |
| dc.identifier.orcid | https://orcid.org/0000-0002-8601-7799 | |
| mit.license | PUBLISHER_CC | en_US |
| mit.metadata.status | Complete | |
