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Stark Interference of Electric and Magnetic Dipole Transitions in the A − X Band of OH

Author(s)
Schewe, H. Christian; Zhang, Dongdong; Meijer, Gerard; Field, Robert W.; Sartakov, Boris G.; Groenenboom, Gerrit C.; van der Avoird, Ad; Vanhaecke, Nicolas; ... Show more Show less
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Abstract
An experimental method is demonstrated that allows determination of the ratio between the electric (E1) and magnetic (M1) transition dipole moments in the A − X band of OH, including their relative sign. Although the transition strengths differ by more than 3 orders of magnitude, the measured M1-to-E1 ratio agrees with the ratio of the ab initio calculated values to within 3%. The relative sign is found to be negative, also in agreement with theory.
Date issued
2016-04
URI
http://hdl.handle.net/1721.1/102240
Department
Massachusetts Institute of Technology. Department of Chemistry
Journal
Physical Review Letters
Publisher
American Physical Society
Citation
Schewe, H. Christian, Dongdong Zhang, Gerard Meijer, Robert W. Field, Boris G. Sartakov, Gerrit C. Groenenboom, Ad van der Avoird, and Nicolas Vanhaecke. “Stark Interference of Electric and Magnetic Dipole Transitions in the A − X Band of OH.” Physical Review Letters 116, no. 15 (April 11, 2016). © 2016 American Physical Society
Version: Final published version
ISSN
0031-9007
1079-7114

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