Mitigating Electronic Current in Molten Flux for the Magnesium SOM Process
Author(s)
Guan, Xiaofei; Gratz, Eric S.; Milshtein, Jarrod D.; Pal, Uday B.; Powell, Adam C.; Milshtein, Jarrod David; ... Show more Show less
Download11663_2014_Article_60.pdf (1003.Kb)
PUBLISHER_POLICY
Publisher Policy
Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use.
Terms of use
Metadata
Show full item recordAbstract
The solid oxide membrane (SOM) process has been used at 1423 K to 1473 K (1150 °C to 1200 °C) to produce magnesium metal by the direct electrolysis of magnesium oxide. MgO is dissolved in a molten MgF[subscript 2]-CaF[subscript 2] ionic flux. An oxygen-ion-conducting membrane, made from yttria-stabilized zirconia (YSZ), separates the cathode and the flux from the anode. During electrolysis, magnesium ions are reduced at the cathode, and Mg[subscript (g)] is bubbled out of the flux into a separate condenser. The flux has a small solubility for magnesium metal which imparts electronic conductivity to the flux. The electronic conductivity decreases the process current efficiency and also degrades the YSZ membrane. Operating the electrolysis cell at low total pressures is shown to be an effective method of reducing the electronic conductivity of the flux. A two steel electrode method for measuring the electronic transference number in the flux was used to quantify the fraction of electronic current in the flux before and after SOM process operation. Potentiodynamic scans, potentiostatic electrolyses, and AC impedance spectroscopy were also used to characterize the SOM process under different operating conditions.
Date issued
2014-03Department
Massachusetts Institute of Technology. Department of Materials Science and EngineeringJournal
Metallurgical and Materials Transactions B
Publisher
Springer US
Citation
Gratz, Eric S., Xiaofei Guan, Jarrod D. Milshtein, Uday B. Pal, and Adam C. Powell. “Mitigating Electronic Current in Molten Flux for the Magnesium SOM Process.” Metallurgical and Materials Transactions B 45, no. 4 (March 29, 2014): 1325–1336.
Version: Author's final manuscript
ISSN
1073-5615
1543-1916