Proof of Tacticity of Stereoregular ROMP Polymers through Post Polymerization Modification

Author(s)
Hyvl, Jakub; Autenrieth, Benjamin; Schrock, Richard Royce
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Abstract
Partial bromination or epoxidation has been used to prove the tacticities of several stereoregular polymers made through ROMP methods with well-defined Mo or W initiators.Tacticities were proven for cis,isotactic and cis,syndiotactic poly(norbornene), poly(3-methyl-3-phenylcyclopropene), and poly(endo,anti-tetracyclododecene). Various limitations can prevent application of these proofs in general to stereoregular polymers prepared through ROMP.
Date issued
2015-04
URI
http://hdl.handle.net/1721.1/108291
Department
Massachusetts Institute of Technology. Department of Chemistry
Journal
Macromolecules
Publisher
American Chemical Society (ACS)
Citation
Hyvl, Jakub; Autenrieth, Benjamin and Schrock, Richard R."Proof of Tacticity of Stereoregular ROMP Polymers through Post Polymerization Modification." Macromolecules 48, no. 9 (May 2015): 3148–3152. © 2015 American Chemical Society
Version: Author's final manuscript
ISSN
0024-9297
1520-5835
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