Proof of Tacticity of Stereoregular ROMP Polymers through Post Polymerization Modification
Author(s)Hyvl, Jakub; Autenrieth, Benjamin; Schrock, Richard Royce
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Partial bromination or epoxidation has been used to prove the tacticities of several stereoregular polymers made through ROMP methods with well-defined Mo or W initiators.Tacticities were proven for cis,isotactic and cis,syndiotactic poly(norbornene), poly(3-methyl-3-phenylcyclopropene), and poly(endo,anti-tetracyclododecene). Various limitations can prevent application of these proofs in general to stereoregular polymers prepared through ROMP.
DepartmentMassachusetts Institute of Technology. Department of Chemistry
American Chemical Society (ACS)
Hyvl, Jakub; Autenrieth, Benjamin and Schrock, Richard R."Proof of Tacticity of Stereoregular ROMP Polymers through Post Polymerization Modification." Macromolecules 48, no. 9 (May 2015): 3148–3152. © 2015 American Chemical Society
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