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dc.contributor.authorLux, Simon F.
dc.contributor.authorPaschos, Odysseas
dc.contributor.authorMaglia, Filippo
dc.contributor.authorLupart, Saskia
dc.contributor.authorLamp, Peter
dc.contributor.authorBachman, Chris
dc.contributor.authorMuy, Sokseiha
dc.contributor.authorGrimaud, Alexis
dc.contributor.authorChang, Hao Hsun
dc.contributor.authorPour, Nir
dc.contributor.authorGiordano, Livia
dc.contributor.authorShao-Horn, Yang
dc.date.accessioned2017-06-02T15:09:19Z
dc.date.available2017-06-02T15:09:19Z
dc.date.issued2015-12
dc.identifier.issn0009-2665
dc.identifier.issn1520-6890
dc.identifier.urihttp://hdl.handle.net/1721.1/109539
dc.description.abstractThis Review is focused on ion-transport mechanisms and fundamental properties of solid-state electrolytes to be used in electrochemical energy-storage systems. Properties of the migrating species significantly affecting diffusion, including the valency and ionic radius, are discussed. The natures of the ligand and metal composing the skeleton of the host framework are analyzed and shown to have large impacts on the performance of solid-state electrolytes. A comprehensive identification of the candidate migrating species and structures is carried out. Not only the bulk properties of the conductors are explored, but the concept of tuning the conductivity through interfacial effects—specifically controlling grain boundaries and strain at the interfaces—is introduced. High-frequency dielectric constants and frequencies of low-energy optical phonons are shown as examples of properties that correlate with activation energy across many classes of ionic conductors. Experimental studies and theoretical results are discussed in parallel to give a pathway for further improvement of solid-state electrolytes. Through this discussion, the present Review aims to provide insight into the physical parameters affecting the diffusion process, to allow for more efficient and target-oriented research on improving solid-state ion conductors.en_US
dc.description.sponsorshipNational Science Foundation (U.S.) (Graduate Research Fellowship (1122374)en_US
dc.description.sponsorshipTaiwan. Ministry of Science and Technology (102-2917-I-564-006-A1)en_US
dc.description.sponsorshipBMW Groupen_US
dc.description.sponsorshipSkoltech-MIT Centeren_US
dc.language.isoen_US
dc.publisherAmerican Chemical Society (ACS)en_US
dc.relation.isversionofhttp://dx.doi.org/10.1021/acs.chemrev.5b00563en_US
dc.rightsArticle is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use.en_US
dc.sourceProf. Shao-Horn via Angie Locknaren_US
dc.titleInorganic Solid-State Electrolytes for Lithium Batteries: Mechanisms and Properties Governing Ion Conductionen_US
dc.title.alternativeInorganic Solid-State Electrolytes for Lithium Batteries: Mechanisms and Properties Governing Ion Conductionen_US
dc.typeArticleen_US
dc.identifier.citationBachman, John Christopher, Sokseiha Muy, Alexis Grimaud, Hao-Hsun Chang, Nir Pour, Simon F. Lux, Odysseas Paschos, et al. “Inorganic Solid-State Electrolytes for Lithium Batteries: Mechanisms and Properties Governing Ion Conduction.” Chemical Reviews 116, no. 1 (January 13, 2016): 140–162.en_US
dc.contributor.departmentMassachusetts Institute of Technology. Materials Processing Centeren_US
dc.contributor.departmentMassachusetts Institute of Technology. Department of Materials Science and Engineeringen_US
dc.contributor.departmentMassachusetts Institute of Technology. Department of Mechanical Engineeringen_US
dc.contributor.departmentMassachusetts Institute of Technology. Research Laboratory of Electronicsen_US
dc.contributor.approverShao-Horn, Yangen_US
dc.contributor.mitauthorBachman, Chris
dc.contributor.mitauthorMuy, Sokseiha
dc.contributor.mitauthorGrimaud, Alexis
dc.contributor.mitauthorChang, Hao Hsun
dc.contributor.mitauthorPour, Nir
dc.contributor.mitauthorGiordano, Livia
dc.contributor.mitauthorShao-Horn, Yang
dc.relation.journalChemical Reviewsen_US
dc.eprint.versionAuthor's final manuscripten_US
dc.type.urihttp://purl.org/eprint/type/JournalArticleen_US
eprint.statushttp://purl.org/eprint/status/PeerRevieweden_US
dspace.orderedauthorsBachman, John Christopher; Muy, Sokseiha; Grimaud, Alexis; Chang, Hao-Hsun; Pour, Nir; Lux, Simon F.; Paschos, Odysseas; Maglia, Filippo; Lupart, Saskia; Lamp, Peter; Giordano, Livia; Shao-Horn, Yangen_US
dspace.embargo.termsNen_US
dc.identifier.orcidhttps://orcid.org/0000-0003-1992-0029
dc.identifier.orcidhttps://orcid.org/0000-0001-6457-9187
dc.identifier.orcidhttps://orcid.org/0000-0002-9966-205X
dc.identifier.orcidhttps://orcid.org/0000-0002-2701-8265
dc.identifier.orcidhttps://orcid.org/0000-0001-7840-6682
mit.licensePUBLISHER_POLICYen_US


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