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Many-body formalism for thermally excited wave packets: A way to connect the quantum regime to the classical regime

Author(s)
Combescot, Monique; Chenu, Aurelia
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Abstract
Free classical particles have well-defined momentum and position, while free quantum particles have well-defined momentum but a position fully delocalized over the sample volume. We develop a many-body formalism based on wave-packet operators that connects these two limits, the thermal energy being distributed between the state spatial extension and its thermal excitation. The corresponding mixed quantum-classical states, which render the Boltzmann operator diagonal, are the physically relevant states when the temperature is finite. The formulation of many-body Hamiltonians in terms of these thermally excited wave packets and the resulting effective scatterings is provided.
Date issued
2017-06
URI
http://hdl.handle.net/1721.1/110586
Department
Massachusetts Institute of Technology. Department of Chemistry
Journal
Physical Review A
Publisher
American Physical Society
Citation
Chenu, Aurélia and Combescot Monique. "Many-body formalism for thermally excited wave packets: A way to connect the quantum regime to the classical regime." Physical Review A 95, 062124 (2017).
Version: Final published version
ISSN
2469-9926
2469-9934

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