Last Glacial Maximum and deglacial abyssal seawater oxygen isotopic ratios

Abstract

An earlier analysis of pore-water salinity (chlorinity) in two deep-sea cores, using terminal constraint methods of control theory, concluded that although a salinity amplification in the abyss was possible during the LGM, it was not required by the data. Here the same methodology is applied to δ[superscript 18]O[subscript w] in the upper 100 m of four deep-sea cores. An ice volume amplification to the isotopic ratio is, again, consistent with the data but not required by it. In particular, results are very sensitive, with conventional diffusion values, to the assumed initial conditions at −100 ky and a long list of noise (uncertainty) assumptions. If the calcite values of δ[superscript 18]O are fully reliable, then published enriched values of the ratio in seawater are necessary to preclude sub-freezing temperatures, but the seawater δ[superscript 18]O in pore fluids does not independently require the conclusion.