| dc.contributor.author | Dengiz, Cagatay | |
| dc.contributor.author | Swager, Timothy M | |
| dc.date.accessioned | 2018-03-27T19:47:40Z | |
| dc.date.available | 2018-03-27T19:47:40Z | |
| dc.date.issued | 2017-04 | |
| dc.date.submitted | 2017-03 | |
| dc.identifier.issn | 0936-5214 | |
| dc.identifier.issn | 1437-2096 | |
| dc.identifier.uri | http://hdl.handle.net/1721.1/114422 | |
| dc.description.abstract | We report the synthesis and characterization of three new classes of push–pull chromophores using [2+2]-cycloaddition reactions of electron-rich alkynes and electron-poor alkenes. Previous investigations have focused on the reactions of cyano-substituted electron acceptors. This study demonstrates that cyano-free electron acceptors, naphtho- and anthradiquinones, can also be used to access extended push–pull systems. The effects of the structural changes on the spectroscopic and electronic properties were investigated by UV/vis spectroscopy. Structures were confirmed by X-ray and NMR analysis in solution. Keywords: homoconjugation - cycloaddition - push–pull - quinones - spirocycles | en_US |
| dc.description.sponsorship | Swiss National Science Foundation (Early Postdoc Mobility Fellowship) | en_US |
| dc.description.sponsorship | United States. Air Force. Office of Scientific Research (FA9550-14-1-0226) | en_US |
| dc.language.iso | en_US | |
| dc.publisher | Thieme Publishing Group | en_US |
| dc.relation.isversionof | http://dx.doi.org/10.1055/s-0036-1588771 | en_US |
| dc.rights | Creative Commons Attribution-Noncommercial-Share Alike | en_US |
| dc.rights.uri | http://creativecommons.org/licenses/by-nc-sa/4.0/ | en_US |
| dc.source | Prof. Swager via Erja Kajosalo | en_US |
| dc.title | Homoconjugated and Spiro Push–Pull Systems: Cycloadditions of Naphtho- and Anthradiquinones with Electron-Rich Alkynes | en_US |
| dc.type | Article | en_US |
| dc.identifier.citation | Dengiz, Cagatay, and Timothy Swager. “Homoconjugated and Spiro Push–Pull Systems: Cycloadditions of Naphtho- and Anthradiquinones with Electron-Rich Alkynes.” Synlett, vol. 28, no. 12, July 2017, pp. 1427–31. | en_US |
| dc.contributor.department | Massachusetts Institute of Technology. Department of Chemistry | en_US |
| dc.contributor.approver | Swager, Timothy M | en_US |
| dc.contributor.mitauthor | Dengiz, Cagatay | |
| dc.contributor.mitauthor | Swager, Timothy M | |
| dc.relation.journal | Synlett | en_US |
| dc.eprint.version | Original manuscript | en_US |
| dc.type.uri | http://purl.org/eprint/type/JournalArticle | en_US |
| eprint.status | http://purl.org/eprint/status/NonPeerReviewed | en_US |
| dspace.orderedauthors | Dengiz, Cagatay; Swager, Timothy | en_US |
| dspace.embargo.terms | N | en_US |
| mit.license | OPEN_ACCESS_POLICY | en_US |
