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dc.contributor.authorRinzler, Charles Cooper
dc.contributor.authorAllanore, Antoine
dc.date.accessioned2018-04-18T17:03:57Z
dc.date.available2018-04-18T17:03:57Z
dc.date.issued2016-12
dc.date.submitted2016-08
dc.identifier.issn1478-6435
dc.identifier.issn1478-6443
dc.identifier.urihttp://hdl.handle.net/1721.1/114781
dc.description.abstractThe thermodynamic origin of a relation between features of the phase diagrams and the electronic properties of molten semiconductors is provided. Leveraging a quantitative connection between electronic properties and entropy, a criterion is derived to establish whether a system will retain its semiconducting properties in the molten phase. It is shown that electronic entropy is critical to the thermodynamics of molten semiconductor systems, driving key features of phase diagrams including, for example, miscibility gaps. Keywords: entropy; electronic entropy; thermopower; molten semiconductoren_US
dc.description.sponsorshipUnited States. Air Force Office of Scientific Research (Grant FA9550-15-1-0046)en_US
dc.language.isoen_US
dc.publisherTaylor & Francisen_US
dc.relation.isversionofhttps://doi.org/10.1080/14786435.2016.1269968en_US
dc.rightsCreative Commons Attribution-Noncommercial-Share Alikeen_US
dc.rights.urihttp://creativecommons.org/licenses/by-nc-sa/4.0/en_US
dc.sourceProf. Allanore via Erja Kajosaloen_US
dc.titleA thermodynamic basis for the electronic properties of molten semiconductors: the role of electronic entropyen_US
dc.typeArticleen_US
dc.identifier.citationRinzler, Charles C., and A. Allanore. “A Thermodynamic Basis for the Electronic Properties of Molten Semiconductors: The Role of Electronic Entropy.” Philosophical Magazine 97, 8 (December 2016): 561–571 © 2016 Informa UK limited, trading as Taylor & Francis groupen_US
dc.contributor.departmentMassachusetts Institute of Technology. Department of Materials Science and Engineeringen_US
dc.contributor.approverAllanore, Antoineen_US
dc.contributor.mitauthorRinzler, Charles Cooper
dc.contributor.mitauthorAllanore, Antoine
dc.relation.journalPhilosophical Magazineen_US
dc.eprint.versionAuthor's final manuscripten_US
dc.type.urihttp://purl.org/eprint/type/JournalArticleen_US
eprint.statushttp://purl.org/eprint/status/PeerRevieweden_US
dspace.orderedauthorsRinzler, Charles C.; Allanore, A.en_US
dspace.embargo.termsNen_US
dc.identifier.orcidhttps://orcid.org/0000-0002-4628-3937
dc.identifier.orcidhttps://orcid.org/0000-0002-2594-0264
mit.licenseOPEN_ACCESS_POLICYen_US


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