dc.contributor.author | Caldwell, Andrew Harvey | |
dc.contributor.author | Lai, E. | |
dc.contributor.author | Gmitter, Andrew John | |
dc.contributor.author | Allanore, Antoine | |
dc.date.accessioned | 2018-11-20T20:40:29Z | |
dc.date.available | 2018-11-20T20:40:29Z | |
dc.date.issued | 2016-09 | |
dc.date.submitted | 2016-09 | |
dc.identifier.issn | 0013-4686 | |
dc.identifier.uri | http://hdl.handle.net/1721.1/119244 | |
dc.description.abstract | The electrochemistry of anodic oxygen evolution on iridium in silicate-containing molten oxides at 1570 °C was experimentally investigated using both direct and alternating current methods. Static and rotating electrode results show the presence of anodic reactions of iridium in addition to oxygen evolution. In the context of electrochemical engineering of molten oxide electrolysis, the results confirm prior theoretical calculations (Allanore, 2013) that suggested an essential role of convection and electrolyte composition on the ability to sustain oxygen evolution at high current densities. In addition, the reported results show that electrochemical measurements in molten oxides coupled with mass-transfer models are complementary characterization tools for oxygen chemistry. Keywords; molten oxides, oxygen evolution, rotating electrode, ac voltammetry, iridium, silicates | en_US |
dc.description.sponsorship | American Iron and Steel Institute | en_US |
dc.description.sponsorship | United States. Office of Naval Research (Contract N00014-11-1-0657) | en_US |
dc.language.iso | en_US | |
dc.publisher | Elsevier | en_US |
dc.relation.isversionof | https://doi.org/10.1016/j.electacta.2016.09.132 | en_US |
dc.rights | Creative Commons Attribution-NonCommercial-NoDerivs License | en_US |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | en_US |
dc.source | Prof. Allanore via Erja Kajosalo | en_US |
dc.title | Influence of mass transfer and electrolyte composition on anodic oxygen evolution in molten oxides | en_US |
dc.type | Article | en_US |
dc.identifier.citation | Caldwell, A. H., et al. “Influence of Mass Transfer and Electrolyte Composition on Anodic Oxygen Evolution in Molten Oxides.” Electrochimica Acta, vol. 219, Nov. 2016, pp. 178–86. | en_US |
dc.contributor.department | Massachusetts Institute of Technology. Department of Materials Science and Engineering | en_US |
dc.contributor.approver | Allanore, Antoine | en_US |
dc.contributor.mitauthor | Caldwell, Andrew Harvey | |
dc.contributor.mitauthor | Lai, E. | |
dc.contributor.mitauthor | Gmitter, Andrew John | |
dc.contributor.mitauthor | Allanore, Antoine | |
dc.relation.journal | Electrochimica Acta | en_US |
dc.eprint.version | Author's final manuscript | en_US |
dc.type.uri | http://purl.org/eprint/type/JournalArticle | en_US |
eprint.status | http://purl.org/eprint/status/PeerReviewed | en_US |
dspace.orderedauthors | Caldwell, A.H.; Lai, E.; Gmitter, A.J.; Allanore, A. | en_US |
dspace.embargo.terms | N | en_US |
dc.identifier.orcid | https://orcid.org/0000-0002-4382-4005 | |
dc.identifier.orcid | https://orcid.org/0000-0002-2594-0264 | |
mit.license | PUBLISHER_CC | en_US |