Conducting Polymer-Based Multifunctional Materials

Abstract

Conducting polymers are employable as low-voltage actuators, sensors, energy storage and delivery components, structural elements, computational circuitry, memory, and electronic components, making them a versatile choice for creating integrated, multifunctional materials and devices. Here we show one such conducting polymer-based, multifunctional system, derived from the versatility of the conducting polymer polypyrrole. Three functions of polypyrrole (actuation, length sensation, and energy storage) have been individually evaluated and cooperatively combined in the synthesis of a multifunctional, polymeric system that actuates, senses strain deformation, and stores energy. The system operates whereby the strain of a polypyrrole actuator is measured by a polypyrrole length sensor, whilst being powered by an array of polypyrrole supercapacitors. Independently, polypyrrole actuators were evaluated at 250 discrete frequencies ranging from 0.01 to 10 Hz using fixed, ±1 V sinusoidal excitation. Polypyrrole length sensors were evaluated using a thin-film dynamic mechanical analyzer for the same range of frequencies with a 2% sinusoidal input strain. Polypyrrole supercapacitors were evaluated using cyclic voltammetry (-1.0 V to +1.0 V; 12.5 to 100 mV/sec) and galvanostatic charge-discharge cycling (0.5 to 2 mA/mg). As an actuator, polypyrrole samples showed measureable actuation strain between 0.001% and 1.6% for the frequency range tested, with amplitude versus frequency decay behavior similar to a first-order low-pass filter. As a length sensor, polypyrrole samples showed linear-elastic behavior up to 3% strain and gauge factors near 4. As a symmetric supercapacitor, polypyrrole had capacitance values higher than 20 kF/kg, energy densities near 20 kJ/kg, and power densities near 2 kW/kg. The evaluation of each component, independently, justified creating a cooperative system composed of these three components operating simultaneously. Polypyrrole supercapacitors provided ample power to excite polypyrrole actuators. Polypyrrole length sensors attached in series to polypyrrole actuators were capable of measuring strain from coupled polypyrrole actuators. Performance metrics and future possibilities regarding conducting polymer-based multifunctional materials are discussed. Topics: Polymers , Multifunctional materials