Poly(para-arylene)s via [2+2+2]
Author(s)Swager, Timothy M; Batson, Joel Marcus
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We report a versatile new synthetic route to poly(para-phenylene)s (PPPs) and related poly(para-arylene)s containing high degrees of substitution not readily available by other methods. Our method transforms highly soluble, alkyne-containing polymers into PPPs via high-yielding, transition metal-mediated [2+2+2] cyclizations.
DepartmentMassachusetts Institute of Technology. Department of Chemistry
ACS Macro Letters
American Chemical Society
Batson, Joel M., and Timothy M. Swager. “Poly( Para-Arylene)s via [2+2+2].” ACS Macro Letters, 1, 9 (September 2012): 1121–23.
Author's final manuscript