Poly(para-arylene)s via [2+2+2]

Author(s)
Swager, Timothy M; Batson, Joel Marcus
Thumbnail
Downloads1-ln1198718640595970-1939656818Hwf1598061610IdV3664940061198718PDF_HI0001.pdf (400.7Kb)
Additional downloads
Terms of use
Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use.
Metadata
Show full item record
Abstract
We report a versatile new synthetic route to poly(para-phenylene)s (PPPs) and related poly(para-arylene)s containing high degrees of substitution not readily available by other methods. Our method transforms highly soluble, alkyne-containing polymers into PPPs via high-yielding, transition metal-mediated [2+2+2] cyclizations.
Date issued
2012-08-27
URI
https://hdl.handle.net/1721.1/121411
Department
Massachusetts Institute of Technology. Department of Chemistry
Journal
ACS Macro Letters
Publisher
American Chemical Society
Citation
Batson, Joel M., and Timothy M. Swager. “Poly( Para-Arylene)s via [2+2+2].” ACS Macro Letters, 1, 9 (September 2012): 1121–23.
Version: Author's final manuscript
ISSN
2161-1653
Collections