| dc.contributor.author | Tanushi, Akira | |
| dc.contributor.author | Radosevich, Alexander T. | |
| dc.date.accessioned | 2020-01-16T13:58:14Z | |
| dc.date.available | 2020-01-16T13:58:14Z | |
| dc.date.issued | 2018-06 | |
| dc.date.submitted | 2018-05 | |
| dc.identifier.issn | 0002-7863 | |
| dc.identifier.issn | 1520-5126 | |
| dc.identifier.uri | https://hdl.handle.net/1721.1/123455 | |
| dc.description.abstract | The synthesis and reactivity of an NPN-chelating ligand containing a nontrigonal phosphorous triamide center (L1 = P(N(o-N(2-pyridyl)C₆H₄)₂) is reported. Metalation of L1 with RuCl2(PPh₃)₃ gives RuCl2(PPh₃)(L1) (2). By contrast, metalation of L1 with RuHCl(CO)(PPh₃)₃ yields RuCl(CO)(PPh₃)(L1[superscript H]) (3), a chelated 10-P-5 ruthenahydridophosphorane, via net insertion into the Ru–H bond. Hydride abstraction from 3 with Ph₃CPF₆ gives [RuCl(CO)(PPh₃)(L1)]PF₆ (4); reaction of 4 with NaBH₄ returns 3. | en_US |
| dc.description.sponsorship | National Institutes of Health (U.S.) (Grant GM114547) | en_US |
| dc.description.sponsorship | National Science Foundation (Grant CHE-1724505) | en_US |
| dc.language.iso | en | |
| dc.publisher | American Chemical Society (ACS) | en_US |
| dc.relation.isversionof | http://dx.doi.org/10.1021/jacs.8b05156 | en_US |
| dc.rights | Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use. | en_US |
| dc.source | PMC | en_US |
| dc.title | Insertion of a Nontrigonal Phosphorus Ligand into a Transition Metal-Hydride: Direct Access to a Metallohydrophosphorane | en_US |
| dc.type | Article | en_US |
| dc.identifier.citation | Tanushi, Akira and Alexander T. Radosevich. "Insertion of a Nontrigonal Phosphorus Ligand into a Transition Metal-Hydride: Direct Access to a Metallohydrophosphorane." Journal of the American Chemical Society 140, 26 (June 2018): 8114-8118 © 2018 American Chemical Society | en_US |
| dc.contributor.department | Massachusetts Institute of Technology. Department of Chemistry | en_US |
| dc.relation.journal | Journal of the American Chemical Society | en_US |
| dc.eprint.version | Author's final manuscript | en_US |
| dc.type.uri | http://purl.org/eprint/type/JournalArticle | en_US |
| eprint.status | http://purl.org/eprint/status/PeerReviewed | en_US |
| dc.date.updated | 2020-01-06T17:23:15Z | |
| dspace.date.submission | 2020-01-06T17:23:18Z | |
| mit.journal.volume | 140 | en_US |
| mit.journal.issue | 26 | en_US |
| mit.metadata.status | Complete | |
