| dc.contributor.author | Neumann, Constanze | |
| dc.contributor.author | Rozeveld, Steven J. | |
| dc.contributor.author | Yu, Mingzhe | |
| dc.contributor.author | Rieth, Adam J. | |
| dc.contributor.author | Dincă, Mircea | |
| dc.date.accessioned | 2020-04-15T13:26:31Z | |
| dc.date.available | 2020-04-15T13:26:31Z | |
| dc.date.issued | 2019-10 | |
| dc.date.submitted | 2019-08 | |
| dc.identifier.issn | 0002-7863 | |
| dc.identifier.issn | 1520-5126 | |
| dc.identifier.uri | https://hdl.handle.net/1721.1/124650 | |
| dc.description.abstract | RuNi nanoparticles supported on a metal-organic framework (RuNi@MOF) and formed in situ from a ruthenium complex enclosed inside a nickel-based MOF act as a highly active catalyst for the Guerbet reaction of ethanol to 1-butanol, providing turnover numbers up to 725 000 Ru-1. Negligible activity of the RuNi@MOF ethanol upgrading catalyst system toward chemically similar 1-butanol makes it possible to synthesize the competent Guerbet substrate 1-butanol with >99% selectivity. Keywords: Ruthenium; Nanoparticles; Ethanol; Metal organic frameworks; Catalysts; Selectivity | en_US |
| dc.description.sponsorship | National Science Foundation. Alan T.Waterman Award (DMR-1645232) | en_US |
| dc.description.sponsorship | National Science Foundation (DMR-1452612) | en_US |
| dc.language.iso | en | |
| dc.publisher | American Chemical Society (ACS) | en_US |
| dc.relation.isversionof | http://dx.doi.org/10.1021/jacs.9b08968 | en_US |
| dc.rights | Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use. | en_US |
| dc.source | MIT web domain | en_US |
| dc.title | Metal-Organic Framework-Derived Guerbet Catalyst Effectively Differentiates between Ethanol and Butanol | en_US |
| dc.type | Article | en_US |
| dc.identifier.citation | Neumann, Constanze et al. "Metal-Organic Framework-Derived Guerbet Catalyst Effectively Differentiates between Ethanol and Butanol." Journal of the American Chemical Society 141, 44 (October 2019): 17477-17481 © 2019 American Chemical Society. | en_US |
| dc.contributor.department | Massachusetts Institute of Technology. Department of Chemistry | en_US |
| dc.relation.journal | Journal of the American Chemical Society | en_US |
| dc.eprint.version | Author's final manuscript | en_US |
| dc.type.uri | http://purl.org/eprint/type/JournalArticle | en_US |
| eprint.status | http://purl.org/eprint/status/PeerReviewed | en_US |
| dc.date.updated | 2019-12-17T16:03:08Z | |
| dspace.date.submission | 2019-12-17T16:03:11Z | |
| mit.journal.volume | 141 | en_US |
| mit.journal.issue | 44 | en_US |
| mit.license | PUBLISHER_POLICY | |
| mit.metadata.status | Complete | |
