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Modular synthesis of polymers containing 2,5-di(thiophenyl)- N-arylpyrrole

Author(s)
Truong, Tran N. B; Savagatrup, Suchol; Jeon, Intak; Swager, Timothy M
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Abstract
A modular and facile route has been developed to synthesize functionalized 2,5-di(thiophen-2-yl)-1-H-arylpyrroles from readily available starting materials. These units are compatible with various polymerization conditions and are versatile building blocks for conjugated polymers. The polymers show high thermal stability and solubility in a number of solvents. Characterization of the polymers reveals a correlation between molecular packing, controllable by polymer design, and charge carrier mobility.
Date issued
2018-06
URI
https://hdl.handle.net/1721.1/125533
Department
Massachusetts Institute of Technology. Department of Chemistry; Massachusetts Institute of Technology. Department of Materials Science and Engineering
Journal
Journal of polymer science. Part A, Polymer chemistry
Publisher
Wiley
Citation
Truong, Tran N. B. et al. “Modular synthesis of polymers containing 2,5-di(thiophenyl)- N-arylpyrrole.” Journal of polymer science. Part A, Polymer chemistry 56 (2018): 1133-1139 © 2018 The Author(s)
Version: Author's final manuscript
ISSN
1099-0518
0887-624X

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