Modular synthesis of polymers containing 2,5-di(thiophenyl)- N-arylpyrrole
Author(s)Truong, Tran N. B; Savagatrup, Suchol; Jeon, Intak; Swager, Timothy M
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A modular and facile route has been developed to synthesize functionalized 2,5-di(thiophen-2-yl)-1-H-arylpyrroles from readily available starting materials. These units are compatible with various polymerization conditions and are versatile building blocks for conjugated polymers. The polymers show high thermal stability and solubility in a number of solvents. Characterization of the polymers reveals a correlation between molecular packing, controllable by polymer design, and charge carrier mobility.
DepartmentMassachusetts Institute of Technology. Department of Chemistry; Massachusetts Institute of Technology. Department of Materials Science and Engineering
Journal of polymer science. Part A, Polymer chemistry
Truong, Tran N. B. et al. “Modular synthesis of polymers containing 2,5-di(thiophenyl)- N-arylpyrrole.” Journal of polymer science. Part A, Polymer chemistry 56 (2018): 1133-1139 © 2018 The Author(s)
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