Interdigitated conducting tetrathiafulvalene-based coordination networks

Author(s)
Bechu, Damien; Xie, Lilia S.; Le Breton, Nolwenn; Choua, Sylvie; Dinca, Mircea; ... Show more
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Abstract
Assembly of a novel ethylenedithio-tetrathiafulvalene (EDT-TTF) derivative bearing two adjacent 4-thiopyridyl groups with M(NCS)2 nodes (M = Fe, Co) leads to two isostructural 1D coordination polymers showing an enhancement of their electronic conductivity by six orders of magnitude (10[superscript -6] vs. 10[superscript -12] S cm[superscript -1), upon surface oxidation by iodine and subsequent generation of EDT-TTF-based radicals.
Date issued
2020-01
URI
https://hdl.handle.net/1721.1/128208
Department
Massachusetts Institute of Technology. Department of Chemistry
Journal
Chemical Communications
Publisher
Royal Society of Chemistry (RSC)
Citation
Bechu, Damien et al. "Interdigitated conducting tetrathiafulvalene-based coordination networks." Chemical Communications 56, 16 (January 2020): 2407-2410 © 2020 The Royal Society of Chemistry
Version: Author's final manuscript
ISSN
1359-7345
1364-548X
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