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dc.contributor.authorWu, Lidong
dc.contributor.authorJi, Xiang
dc.contributor.authorKong, Jing
dc.date.accessioned2022-08-02T19:21:41Z
dc.date.available2021-09-20T18:21:33Z
dc.date.available2022-08-02T19:21:41Z
dc.date.issued2019
dc.identifier.urihttps://hdl.handle.net/1721.1/132265.2
dc.description.abstract© 2019 American Chemical Society. Bisphenol A (BPA) is not only a widely used chemical but also a toxic pollutant, and its biodegradation in an aqueous environment is hard due to its near insolubility in water. While the enzyme tyrosinase can oxidize BPA in organic solvents, it does so only very slowly. In the present study, we have found that in toluene the catalytic activity of tyrosinase deposited onto coated mesoporous carbon is significantly enhanced when the support is precoated with polyethylenimine. The resultant enzymatically formed o-quinone is both easily recoverable and potentially useful monomer. As a particular example, the o-quinone readily reacts with diamine in toluene to form poly(amino-quinone) polymers, which are suitable for anticorrosion, energy storage, or biosensor applications.en_US
dc.language.isoen
dc.publisherAmerican Chemical Society (ACS)en_US
dc.relation.isversionof10.1021/ACSOMEGA.9B01945en_US
dc.rightsArticle is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use.en_US
dc.sourceACSen_US
dc.titlePolymer-Coated Mesoporous Carbon as Enzyme Platform for Oxidation of Bisphenol A in Organic Solventsen_US
dc.typeArticleen_US
dc.contributor.departmentMassachusetts Institute of Technology. Department of Chemistryen_US
dc.contributor.departmentMassachusetts Institute of Technology. Research Laboratory of Electronicsen_US
dc.relation.journalACS Omegaen_US
dc.eprint.versionFinal published versionen_US
dc.type.urihttp://purl.org/eprint/type/JournalArticleen_US
eprint.statushttp://purl.org/eprint/status/PeerRevieweden_US
dc.date.updated2021-01-08T16:15:30Z
dspace.orderedauthorsWu, L; Ji, X; Kong, Jen_US
dspace.date.submission2021-01-08T16:15:35Z
mit.journal.volume4en_US
mit.journal.issue15en_US
mit.licensePUBLISHER_POLICY
mit.metadata.statusPublication Information Neededen_US


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