dc.contributor.author | He, Xin | |
dc.contributor.author | Looker, Benjamin G. | |
dc.contributor.author | Dinh, Kimberly T. | |
dc.contributor.author | Stubbs, Amanda W. | |
dc.contributor.author | Chen, Tianyang | |
dc.contributor.author | Meyer, Randall J. | |
dc.contributor.author | Serna, Pedro | |
dc.contributor.author | Román-Leshkov, Yuriy | |
dc.contributor.author | Lancaster, Kyle M. | |
dc.contributor.author | Dincă, Mircea | |
dc.date.accessioned | 2022-03-08T15:46:12Z | |
dc.date.available | 2022-03-08T13:14:38Z | |
dc.date.available | 2022-03-08T15:46:12Z | |
dc.date.issued | 2020-06 | |
dc.date.submitted | 2020-06 | |
dc.identifier.issn | 2155-5435 | |
dc.identifier.uri | https://hdl.handle.net/1721.1/141056.2 | |
dc.description.abstract | © 2020 American Chemical Society. The rates of catalytic oxidation of cyclohexane and CO are 4 and 20 times higher, respectively, with Cu supported on a cerium-based metal-organic framework (MOF) than on the structurally analogous zirconium material. Both Ce- and Zr-based copper catalysts feature uncommon three-coordinate CuII sites bearing different nuclearities, as determined by Cu K-edge extended X-ray absorption fine structure analysis. These results offer molecular-level understanding of the metal-support interface in MOF catalysts and establish correlations with the more established literature on zirconia- and ceria-supported heterogeneous catalysis. | en_US |
dc.language.iso | en | |
dc.publisher | American Chemical Society (ACS) | en_US |
dc.relation.isversionof | http://dx.doi.org/10.1021/ACSCATAL.0C02493 | en_US |
dc.rights | Creative Commons Attribution-Noncommercial-Share Alike | en_US |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-sa/4.0/ | en_US |
dc.source | DOE repository | en_US |
dc.title | Cerium(IV) Enhances the Catalytic Oxidation Activity of Single-Site Cu Active Sites in MOFs | en_US |
dc.type | Article | en_US |
dc.identifier.citation | He, Xin, Looker, Benjamin G, Dinh, Kimberly T, Stubbs, Amanda W, Chen, Tianyang et al. 2020. "Cerium(IV) Enhances the Catalytic Oxidation Activity of Single-Site Cu Active Sites in MOFs." ACS Catalysis, 10 (14). | en_US |
dc.contributor.department | Massachusetts Institute of Technology. Department of Chemistry | |
dc.contributor.department | Massachusetts Institute of Technology. Department of Chemical Engineering | |
dc.relation.journal | ACS Catalysis | en_US |
dc.eprint.version | Author's final manuscript | en_US |
dc.type.uri | http://purl.org/eprint/type/JournalArticle | en_US |
eprint.status | http://purl.org/eprint/status/PeerReviewed | en_US |
dc.date.updated | 2022-03-08T12:57:15Z | |
dspace.orderedauthors | He, X; Looker, BG; Dinh, KT; Stubbs, AW; Chen, T; Meyer, RJ; Serna, P; Román-Leshkov, Y; Lancaster, KM; Dincă, M | en_US |
dspace.date.submission | 2022-03-08T12:57:17Z | |
mit.journal.volume | 10 | en_US |
mit.journal.issue | 14 | en_US |
mit.license | OPEN_ACCESS_POLICY | |
mit.metadata.status | Authority Work Needed | en_US |