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dc.contributor.authorHe, Xin
dc.contributor.authorLooker, Benjamin G.
dc.contributor.authorDinh, Kimberly T.
dc.contributor.authorStubbs, Amanda W.
dc.contributor.authorChen, Tianyang
dc.contributor.authorMeyer, Randall J.
dc.contributor.authorSerna, Pedro
dc.contributor.authorRomán-Leshkov, Yuriy
dc.contributor.authorLancaster, Kyle M.
dc.contributor.authorDincă, Mircea
dc.date.accessioned2022-03-08T15:46:12Z
dc.date.available2022-03-08T13:14:38Z
dc.date.available2022-03-08T15:46:12Z
dc.date.issued2020-06
dc.date.submitted2020-06
dc.identifier.issn2155-5435
dc.identifier.urihttps://hdl.handle.net/1721.1/141056.2
dc.description.abstract© 2020 American Chemical Society. The rates of catalytic oxidation of cyclohexane and CO are 4 and 20 times higher, respectively, with Cu supported on a cerium-based metal-organic framework (MOF) than on the structurally analogous zirconium material. Both Ce- and Zr-based copper catalysts feature uncommon three-coordinate CuII sites bearing different nuclearities, as determined by Cu K-edge extended X-ray absorption fine structure analysis. These results offer molecular-level understanding of the metal-support interface in MOF catalysts and establish correlations with the more established literature on zirconia- and ceria-supported heterogeneous catalysis.en_US
dc.language.isoen
dc.publisherAmerican Chemical Society (ACS)en_US
dc.relation.isversionofhttp://dx.doi.org/10.1021/ACSCATAL.0C02493en_US
dc.rightsCreative Commons Attribution-Noncommercial-Share Alikeen_US
dc.rights.urihttp://creativecommons.org/licenses/by-nc-sa/4.0/en_US
dc.sourceDOE repositoryen_US
dc.titleCerium(IV) Enhances the Catalytic Oxidation Activity of Single-Site Cu Active Sites in MOFsen_US
dc.typeArticleen_US
dc.identifier.citationHe, Xin, Looker, Benjamin G, Dinh, Kimberly T, Stubbs, Amanda W, Chen, Tianyang et al. 2020. "Cerium(IV) Enhances the Catalytic Oxidation Activity of Single-Site Cu Active Sites in MOFs." ACS Catalysis, 10 (14).en_US
dc.relation.journalACS Catalysisen_US
dc.eprint.versionAuthor's final manuscripten_US
dc.type.urihttp://purl.org/eprint/type/JournalArticleen_US
eprint.statushttp://purl.org/eprint/status/PeerRevieweden_US
dc.date.updated2022-03-08T12:57:15Z
dspace.orderedauthorsHe, X; Looker, BG; Dinh, KT; Stubbs, AW; Chen, T; Meyer, RJ; Serna, P; Román-Leshkov, Y; Lancaster, KM; Dincă, Men_US
dspace.date.submission2022-03-08T12:57:17Z
mit.journal.volume10en_US
mit.journal.issue14en_US
mit.licenseOPEN_ACCESS_POLICY
mit.metadata.statusAuthority Work Neededen_US


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