| dc.contributor.author | Wakefield, Herbert | |
| dc.contributor.author | Melvin, Sophia J | |
| dc.contributor.author | Jiang, Jennifer | |
| dc.contributor.author | Kevlishvili, Ilia | |
| dc.contributor.author | Siegler, Maxime A | |
| dc.contributor.author | Craig, Stephen L | |
| dc.contributor.author | Kulik, Heather J | |
| dc.contributor.author | Klausen, Rebekka S | |
| dc.date.accessioned | 2025-09-30T20:14:41Z | |
| dc.date.available | 2025-09-30T20:14:41Z | |
| dc.date.issued | 2024-04-05 | |
| dc.identifier.uri | https://hdl.handle.net/1721.1/162847 | |
| dc.description.abstract | Second row elements in small- and medium-rings modulate strain. Herein we report the synthesis of two novel oligosilyl-containing cycloalkynes that exhibit angle-strain, as observed by X-ray crystallography. However, the angle-strained sila-cyclooctynes are sluggish participants in cycloadditions with benzyl azide. A distortion-interaction model analysis based on density functional theory calculations was performed. | en_US |
| dc.language.iso | en | |
| dc.publisher | Royal Society of Chemistry | en_US |
| dc.relation.isversionof | 10.1039/d4cc00439f | en_US |
| dc.rights | Creative Commons Attribution-Noncommercial-ShareAlike | en_US |
| dc.rights.uri | http://creativecommons.org/licenses/by-nc-sa/4.0/ | en_US |
| dc.source | PubMed Central | en_US |
| dc.title | Angle-strained sila-cycloalkynes | en_US |
| dc.type | Article | en_US |
| dc.identifier.citation | Wakefield, Herbert, Melvin, Sophia J, Jiang, Jennifer, Kevlishvili, Ilia, Siegler, Maxime A et al. 2024. "Angle-strained sila-cycloalkynes." Chemical Communications, 60 (36). | |
| dc.contributor.department | Massachusetts Institute of Technology. Department of Chemical Engineering | en_US |
| dc.contributor.department | Massachusetts Institute of Technology. Department of Chemistry | en_US |
| dc.relation.journal | Chemical Communications | en_US |
| dc.eprint.version | Author's final manuscript | en_US |
| dc.type.uri | http://purl.org/eprint/type/JournalArticle | en_US |
| eprint.status | http://purl.org/eprint/status/PeerReviewed | en_US |
| dc.date.updated | 2025-09-30T20:08:07Z | |
| dspace.orderedauthors | Wakefield, H; Melvin, SJ; Jiang, J; Kevlishvili, I; Siegler, MA; Craig, SL; Kulik, HJ; Klausen, RS | en_US |
| dspace.date.submission | 2025-09-30T20:08:09Z | |
| mit.journal.volume | 60 | en_US |
| mit.journal.issue | 36 | en_US |
| mit.license | OPEN_ACCESS_POLICY | |
| mit.metadata.status | Authority Work and Publication Information Needed | en_US |
