Muon-spin spectroscopy of the organometallic spin-1/2 kagome-lattice compound Cu(1,3-benzenedicarboxylate)

Abstract

Using muon-spin resonance, we examine the organometallic hybrid compound Cu(1,3-benzenedicarboxylate) [Cu(1,3-bdc)], which has structurally perfect spin-1/2 copper kagome planes separated by pure organic linkers. This compound has antiferromagnetic interactions with Curie-Weiss temperature of −33 K. We found slowing down of spin fluctuations starting at T=1.8 K and that the state at T→0 is quasistatic with no long-range order and extremely slow spin fluctuations at a rate of 3.6 μs[superscript −1]. This indicates that Cu(1,3-bdc) behaves as expected from a kagome magnet and could serve as a model kagome compound.