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The influence of dissipation on the quantum-classical correspondence: Stability of stochastic trajectories

Author(s)
Kryvohuz, Maksym; Cao, Jianshu
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Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use.

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Abstract
The quantum-classical correspondence in the presence of dissipation is studied. The semiclassical expression for the linear response function of an anharmonic system is expressed in a series containing classical stability matrix elements, which can diverge due to the chaotic behavior of stochastic trajectories. The presence of dissipation in most cases removes the divergence of higher-order correction terms, thus suppressing quantum effects and making the system more classical. The regime of system-bath coupling, which makes quantum dynamics completely classical, is obtained in terms of friction, temperature, and anharmonicity. Special cases when bath coupling may lead to enhancement of quantum effects are discussed.
Date issued
2009-06
URI
http://hdl.handle.net/1721.1/62189
Department
Massachusetts Institute of Technology. Department of Chemistry
Journal
Journal of Chemical Physics
Publisher
American Institute of Physics
Citation
Kryvohuz, Maksym, and Jianshu Cao. “The Influence of Dissipation on the Quantum-classical Correspondence: Stability of Stochastic Trajectories.” The Journal of Chemical Physics 130.23 (2009) : 234107. © 2009 American Institute of Physics
Version: Final published version
ISSN
0021-9606

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