| dc.contributor.author | Cummins, Christopher C. | |
| dc.contributor.author | Piro, Nicholas A. | |
| dc.date.accessioned | 2011-06-30T14:53:53Z | |
| dc.date.available | 2011-06-30T14:53:53Z | |
| dc.date.issued | 2009-01 | |
| dc.date.submitted | 2008-09 | |
| dc.identifier.issn | 0570-0833 | |
| dc.identifier.uri | http://hdl.handle.net/1721.1/64717 | |
| dc.description.abstract | An acyl triphosphirene ligand transfers an O atom to Nb to liberate the putative triphosphacyclobutadiene intermediate [RCP3{W(CO)5}2], which engages in [2+4]-cycloaddition reactions with an organic diene and a phosphaalkyne (see scheme; P orange, O red, W violet, C white). The latter reaction yields the Dewar isomer of a tetraphosphabenzene, which can be converted to a tetraphosphabenzvalene containing a Z-diphosphene. | en_US |
| dc.description.sponsorship | National Science Foundation (U.S.) (grant CHE-719157) | en_US |
| dc.language.iso | en_US | |
| dc.publisher | WILEY-VCH | en_US |
| dc.relation.isversionof | http://dx.doi.org/10.1002/anie.200804432 | en_US |
| dc.rights | Creative Commons Attribution-Noncommercial-Share Alike 3.0 | en_US |
| dc.rights.uri | http://creativecommons.org/licenses/by-nc-sa/3.0/ | en_US |
| dc.source | Prof. Christopher Cummins | en_US |
| dc.title | Tetraphosphabenzenes Obtained via a Triphosphacyclobutadiene Intermediate | en_US |
| dc.type | Article | en_US |
| dc.identifier.citation | Piro, N. and Cummins, C. (2009), Tetraphosphabenzenes Obtained via a Triphosphacyclobutadiene Intermediate. Angewandte Chemie International Edition, 48: 934–938. doi: 10.1002/anie.200804432 | en_US |
| dc.contributor.department | Massachusetts Institute of Technology. Department of Chemistry | en_US |
| dc.contributor.approver | Cummins, Christopher C. | |
| dc.contributor.mitauthor | Cummins, Christopher C. | |
| dc.contributor.mitauthor | Piro, Nicholas A. | |
| dc.relation.journal | Angewandte Chemie International Edition | en_US |
| dc.eprint.version | Author's final manuscript | en_US |
| dc.type.uri | http://purl.org/eprint/type/JournalArticle | en_US |
| eprint.status | http://purl.org/eprint/status/PeerReviewed | en_US |
| dspace.orderedauthors | Piro, Nicholas A.; Cummins, Christopher C. | en |
| dc.identifier.orcid | https://orcid.org/0000-0003-2568-3269 | |
| mit.license | OPEN_ACCESS_POLICY | en_US |
| mit.metadata.status | Complete | |
